发明名称 |
Non-aqueous electrolyte secondary battery |
摘要 |
Disclosed is a non-aqueous electrolyte secondary battery using a polyanion compound or a lithium nickelate as a positive electrode active material, suppressing the elution of a transition metal from the polyanion compound or ameliorating the deterioration of a binder by a residual alkali component, and provides a non-aqueous electrolyte secondary battery having a negative electrode intercalating and deintercalating lithium ions, a positive electrode containing a lithium-containing compound as a positive electrode active material, and a non-aqueous electrolyte with a lithium salt dissolved in organic solvent. The lithium-containing compound is a polyanion compound or a lithium nickelate. The non-aqueous electrolyte contains a fluorosilane compound:;;R1 to R3: alkyl group having 1-8 carbon(s), an alkenyl group having 2-8 carbons, a cycloalkyl group having 5-8 carbons, an aryl group having 6-8 carbons or a fluorine atom. R4: alkylene group having 1-8 carbon(s) or an alkylene group having 4-8 carbons having an ether group. |
申请公布号 |
US9023536(B2) |
申请公布日期 |
2015.05.05 |
申请号 |
US201113823055 |
申请日期 |
2011.10.13 |
申请人 |
Adeka Corporation |
发明人 |
Taki Takayuki;Ohnuma Yuyu;Shibuya Atsuki;Watanabe Hiroaki;Umemoto Hisashi;Usami Kyohei;Yamada Manabu |
分类号 |
H01M6/16;H01M10/056;H01M4/525;H01M10/0525;H01M10/0567;H01M4/58 |
主分类号 |
H01M6/16 |
代理机构 |
Young & Thompson |
代理人 |
Young & Thompson |
主权项 |
1. A non-aqueous electrolyte secondary battery having a negative electrode that is capable of intercalating and deintercalating lithium ions, a positive electrode containing a lithium-containing compound as a positive electrode active material, and a non-aqueous electrolyte in which a lithium salt is dissolved in an organic solvent,
wherein the lithium-containing compound is a polyanion compound or a lithium nickelate, and the non-aqueous electrolyte contains a fluorosilane compound represented by the following general formula (1): wherein R1 to R3 each independently represent an alkyl group having 1 to 8 carbon(s) or a fluorine atom, and R4 represents an alkylene group having 1 to 8 carbon(s) or an alkylene group having 4 to 8 carbons having an ether group. |
地址 |
Tokyo JP |