发明名称 Method for controlling 2-phenyl isomer content of linear alkylbenzene and catalyst used in the method
摘要 A method for controlling 2-isomer content in linear alkylbenzene obtained by alkylating benzene with olefins and catalyst used in the method.
申请公布号 US9024101(B2) 申请公布日期 2015.05.05
申请号 US201314053250 申请日期 2013.10.14
申请人 UOP LLC 发明人 Riley Mark G.;Jan Deng-Yang;Sohn Stephen W.
分类号 C07C2/66;B01J29/80;B01J29/08;B01J29/18;B01J29/50;B01J29/60;B01J29/70;B01J37/00 主分类号 C07C2/66
代理机构 代理人
主权项 1. A process for alkylating a benzene with an olefin comprising reacting a substantially linear olefin having at least 10 carbon atoms with a benzene under alkylation reaction conditions in the presence of a catalyst to produce alkylated benzene, said catalyst comprising a first catalyst containing faujasite comprises at least about 16.5 wt. percent rare earth selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, other rare earths typically associated with the named rare earths, and blends thereof, and a second catalyst component zeolite selected from the group consisting of BPH/UZM-4; wherein the alkylation reaction is operated in the presence of water, and the water content is maintained in the range from bone dry to about 100 ppm.
地址 Des Plaines IL US