发明名称 ニッケルマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに非水系電解質二次電池
摘要 PROBLEM TO BE SOLVED: To provide nickel manganese composite hydroxide particles having high surface Mn/Ni ratio and high grain size uniformity in which dispersibility of the active material in a positive electrode can be improved, and to provide a production method thereof.SOLUTION: When producing a nickel manganese composite hydroxide by crystallization reaction, nucleation is performed by controlling the pH value of an aqueous solution for nucleation containing a metal compound containing nickel and a metal compound containing manganese and an ammonium ion supply body to be 12.0-13.4 measured on the basis of a liquid temperature of 25°C. Subsequently, the nuclei are grown by controlling the pH value of an aqueous solution for growing the particles containing the nuclei thus formed to be 10.5-12.0 measured on the basis of a liquid temperature of 25°C and lower than the pH value in the nucleation process, and the Mn/Ni ratio of the liquid part in the solution is increased on the way of crystallization.
申请公布号 JP5708277(B2) 申请公布日期 2015.04.30
申请号 JP20110127342 申请日期 2011.06.07
申请人 发明人
分类号 H01M4/525;C01G53/00;H01M4/505 主分类号 H01M4/525
代理机构 代理人
主权项
地址