发明名称 FLAME RETARDANT PRECURSORS, POLYMERS PREPARED FROM SUCH PRECURSORS, AND FLAME RESISTANT FABRICS TREATED WITH SUCH POLYMERS
摘要 A composition comprises at least one condensed phosphorus compound. The condensed phosphorus compound is produced by reacting together in a condensation reaction a nitrogen compound and a phosphonium compound. A phosphorus-containing polymer is produced by reacting in a condensation reaction a hydroxyalkylphosphonium compound to produce an intermediate polymer and then oxidizing phosphorus atoms in the intermediate polymer to yield a polymer comprising phosphine oxide groups.
申请公布号 US2015118931(A1) 申请公布日期 2015.04.30
申请号 US201414520660 申请日期 2014.10.22
申请人 MILLIKEN & COMPANY 发明人 Gerhardt Warren W.;Spruell Jason M.;Valenta Petr;Mondal Rajib;McBride Daniel T.;Keller Keith A.
分类号 C08G79/04;D06M15/673;C09K21/12 主分类号 C08G79/04
代理机构 代理人
主权项 1. A composition comprising at least one condensed phosphorus compound, the condensed phosphorus compound being produced by reacting together in a condensation reaction (a) a nitrogen compound conforming to the structure of Formula (N)wherein RN1 is selected from the group consisting of an oxygen atom, a sulfur atom, and a N—H group, and RN2 and RN3 are independently selected from the group consisting of hydrogen, hydrocarbyl groups, substituted hydrocarbyl groups, acyl groups, and silyl groups; and (b) a phosphonium compound conforming to the structure of Formula (P)wherein the variable a is a positive integer; each R1 is selected from the group consisting of hydrogen, C1-C3 alkyl groups, C1-C3 haloalkyl groups, C2-C3 alkenyl groups, and C2-C3 haloalkenyl groups; X is an anion selected from the group consisting of halides, sulfate, hydrogen sulfate, phosphate, acetate, carbonate, bicarbonate, borate, and hydroxide; b is a negative integer representing the charge of the anion X; and a is equal to (-b); wherein the nitrogen compound and the phosphonium compound are reacted together in a ratio of 1 to 3 molar equivalents of nitrogen compound to 1 molar equivalent of phosphonium cations; and wherein about 30 mol. % or less of the condensed phosphorus compounds contained in the composition comprise moieties conforming to the structure of Formula (B)
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