CATALYST FOR POLYMER SOLID ELECTROLYTE TYPE FUEL-CELL AND METHOD FOR PRODUCING CATALYST FOR POLYMER SOLID ELECTROLYTE TYPE FUEL-CELL

摘要

The present invention relates to a catalyst for a fuel cell containing polymer solid electrolyte, which catalyst contains platinum/ruthenium on a carrier in proportions of 2-4 : 8-6 on a mol basis and exhibits excellent resistance to catalyst poisoning attributed to carbon monoxide. In the present invention, there is disclosed a method for producing the catalyst, which includes adding an alcohol to a mixture of an aqueous solution of a ruthenium compound and a platinum catalyst, reducing ruthenium, and causing ruthenium to precipitate at a reaction temperature between 60 DEG C and the boiling point of the mixture after addition of alcohol. A suitable alcohol may be ethanol or methanol in the concentration of 5-15 vol.% based on the total volume of the mixture, and a suitable heating temperature is in the vicinity of the boiling point of the mixture to which ethanol or methanol has been added. According to the present method, there can be produced a platinum/ruthenium catalyst for a fuel cell containing polymer solid electrolyte, which catalyst contains platinum particles and ruthenium particles in proximity to one another on a carrier without causing aggregation and exhibits excellent resistance to catalyst poisoning attributed to carbon monoxide.