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一种配合物[Cu<sub>2</sub>(L<sup>13</sup>)(L<sup>14</sup>)]·(CH<sub>3</sub>OH)，其特征在于[Cu<sub>2</sub>(L<sup>13</sup>)(L<sup>14</sup>)]·(CH<sub>3</sub>OH)的分子式为：C<sub>72</sub>H<sub>70</sub>Cu<sub>2</sub>N<sub>18</sub>O<sub>21</sub>，分子量为：1650.53，HL<sup>13</sup>＝(4S)‑4,6‑二乙基3‑甲基4‑(5‑(甲酯基)‑2‑(6‑甲基吡啶)‑3‑氧‑2,3‑二氢‑1氢‑吡唑)‑1,8‑二(6‑甲基吡啶)‑9‑氧‑1,2,7,8‑四氮杂螺[[4.4]壬‑6‑烯‑3,4,6‑三甲酸甲酯；HL<sup>14</sup>＝(4S)‑4‑乙基3,6‑二甲基4‑(5‑(甲酯基)‑2‑(6‑甲基吡啶)‑3‑氧‑2,3‑二氢‑1氢‑吡唑)‑1,8‑二(6‑甲基吡啶)‑9‑氧‑1,2,7,8‑四氮杂螺[4.4]壬‑6‑烯‑3,4,6‑三甲酸甲酯，晶体结构参数表见表一，键长键角数据见表二；具有良好的抗肿瘤活性；所述配合物[Cu<sub>2</sub>(L<sup>13</sup>)(L<sup>14</sup>)]·(CH<sub>3</sub>OH)的原位合成方法具体步骤为：(1)将0.07‑0.14克分析纯1‑(6‑甲基吡啶)‑5‑羟基‑1氢‑吡唑‑3‑甲酸甲酯，0.05‑0.15克分析纯三水硝酸铜溶于10‑20毫升体积比为1：1的无水乙腈和无水乙醇的混合溶液中；(2)将步骤(1)所制得的溶液转入聚四氟乙烯的反应釜中，在80‑90℃下反应60‑80小时，降温至室温，过滤，滤液置于室温下自然挥发结晶，16天后得到单晶级[Cu<sub>2</sub>(L<sup>13</sup>)(L<sup>14</sup>)]·(CH<sub>3</sub>OH)配合物，其晶体学参数见表一，键长键角数据见表二；表一：[Cu<sub>2</sub>(L<sup>13</sup>)(L<sup>14</sup>)]·(CH<sub>3</sub>OH)的晶体学参数<img file="FDA0000639132480000011.GIF" wi="1340" he="1541" />表二：[Cu<sub>2</sub>(L<sup>13</sup>)(L<sup>14</sup>)]·(CH<sub>3</sub>OH)的键长<img file="FDA0000639132480000021.GIF" wi="86" he="78" />和键角(°)<tables num="0001" id="ctbl0001"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="24%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="24%" /><tbody><row><entry morerows="1">Cu1‑N16</entry><entry morerows="1">2.001(3)</entry><entry morerows="1">C57‑C56</entry><entry morerows="1">1.384(7)</entry></row><row><entry morerows="1">Cu1‑N3</entry><entry morerows="1">1.978(3)</entry><entry morerows="1">C7‑C8</entry><entry morerows="1">1.483(6)</entry></row><row><entry morerows="1">Cu1‑N18</entry><entry morerows="1">2.034(3)</entry><entry morerows="1">C31‑C30</entry><entry morerows="1">1.384(6)</entry></row><row><entry morerows="1">Cu1‑N1</entry><entry morerows="1">2.039(4)</entry><entry morerows="1">C31‑C32</entry><entry morerows="1">1.374(7)</entry></row><row><entry morerows="1">Cu2‑N7</entry><entry morerows="1">2.023(3)</entry><entry morerows="1">C62‑C61</entry><entry morerows="1">1.482(5)</entry></row><row><entry morerows="1">Cu2‑N10</entry><entry morerows="1">2.043(3)</entry><entry morerows="1">C58‑C59</entry><entry morerows="1">1.508(6)</entry></row><row><entry morerows="1">Cu2‑N9</entry><entry morerows="1">2.068(3)</entry><entry morerows="1">N2‑C6</entry><entry morerows="1">1.408(5)</entry></row><row><entry morerows="1">Cu2‑N12</entry><entry morerows="1">1.998(3)</entry><entry morerows="1">C69‑C70</entry><entry morerows="1">1.371(6)</entry></row><row><entry morerows="1">O3‑C10</entry><entry morerows="1">1.256(5)</entry><entry morerows="1">C69‑C68</entry><entry morerows="1">1.377(7)</entry></row><row><entry morerows="1">O15‑C50</entry><entry morerows="1">1.318(5)</entry><entry morerows="1">O1‑C8</entry><entry morerows="1">1.210(5)</entry></row><row><entry morerows="1">O15‑C51</entry><entry morerows="1">1.467(6)</entry><entry morerows="1">C29‑C25</entry><entry morerows="1">1.553(6)</entry></row><row><entry morerows="1">O17‑C48</entry><entry morerows="1">1.331(5)</entry><entry morerows="1">C40‑C41</entry><entry morerows="1">1.499(6)</entry></row><row><entry morerows="1">O17‑C49</entry><entry morerows="1">1.434(5)</entry><entry morerows="1">C23‑C22</entry><entry morerows="1">1.356(7)</entry></row><row><entry morerows="1">C60‑C53</entry><entry morerows="1">1.583(5)</entry><entry morerows="1">C23‑C24</entry><entry morerows="1">1.508(7)</entry></row><row><entry morerows="1">C60‑N14</entry><entry morerows="1">1.468(5)</entry><entry morerows="1">C67‑C68</entry><entry morerows="1">1.371(6)</entry></row><row><entry morerows="1">C60‑C65</entry><entry morerows="1">1.553(5)</entry><entry morerows="1">C70‑C71</entry><entry morerows="1">1.499(7)</entry></row><row><entry morerows="1">C60‑C61</entry><entry morerows="1">1.505(5)</entry><entry morerows="1">C55‑C56</entry><entry morerows="1">1.372(7)</entry></row><row><entry morerows="1">O14‑C50</entry><entry morerows="1">1.194(5)</entry><entry morerows="1">O8‑C27</entry><entry morerows="1">1.190(6)</entry></row><row><entry morerows="1">C53‑C46</entry><entry morerows="1">1.503(5)</entry><entry morerows="1">C6‑C5</entry><entry morerows="1">1.390(6)</entry></row><row><entry morerows="1">C53‑C50</entry><entry morerows="1">1.557(5)</entry><entry morerows="1">C2‑C3</entry><entry morerows="1">1.365(7)</entry></row><row><entry morerows="1">C53‑C47</entry><entry morerows="1">1.532(5)</entry><entry morerows="1">C2‑C1</entry><entry morerows="1">1.491(7)</entry></row><row><entry morerows="1">N6‑C19</entry><entry morerows="1">1.328(6)</entry><entry morerows="1">C22‑C21</entry><entry morerows="1">1.377(8)</entry></row><row><entry morerows="1">N6‑C23</entry><entry morerows="1">1.353(6)</entry><entry morerows="1">C37‑C38</entry><entry morerows="1">1.365(7)</entry></row><row><entry morerows="1">O18‑C65</entry><entry morerows="1">1.207(5)</entry><entry morerows="1">C3‑C4</entry><entry morerows="1">1.358(7)</entry></row><row><entry morerows="1">C36‑N10</entry><entry morerows="1">1.340(5)</entry><entry morerows="1">C34‑C33</entry><entry morerows="1">1.395(7)</entry></row><row><entry morerows="1">C36‑N11</entry><entry morerows="1">1.403(5)</entry><entry morerows="1">C34‑C35</entry><entry morerows="1">1.498(7)</entry></row><row><entry morerows="1">C36‑C37</entry><entry morerows="1">1.383(6)</entry><entry morerows="1">C33‑C32</entry><entry morerows="1">1.356(7)</entry></row><row><entry morerows="1">N7‑N8</entry><entry morerows="1">1.392(4)</entry><entry morerows="1">C5‑C4</entry><entry morerows="1">1.368(7)</entry></row><row><entry morerows="1">N7‑C26</entry><entry morerows="1">1.276(5)</entry><entry morerows="1">C51‑C52</entry><entry morerows="1">1.261(11)</entry></row><row><entry morerows="1">N16‑N17</entry><entry morerows="1">1.395(4)</entry><entry morerows="1">C63‑C64</entry><entry morerows="1">1.366(19)</entry></row><row><entry morerows="1">N16‑C61</entry><entry morerows="1">1.291(5)</entry><entry morerows="1">C14‑C15</entry><entry morerows="1">1.121(12)</entry></row><row><entry morerows="1">O13‑C45</entry><entry morerows="1">1.250(4)</entry><entry morerows="1">C72‑O21</entry><entry morerows="1">1.550(10)</entry></row><row><entry morerows="1">N15‑C54</entry><entry morerows="1">1.326(5)</entry><entry morerows="1">O19‑C62</entry><entry morerows="1">1.177(5)</entry></row><row><entry morerows="1">N15‑C58</entry><entry morerows="1">1.331(5)</entry><entry morerows="1">N17‑C66</entry><entry morerows="1">1.414(5)</entry></row><row><entry morerows="1">N3‑C7</entry><entry morerows="1">1.328(5)</entry><entry morerows="1">N17‑C65</entry><entry morerows="1">1.391(5)</entry></row><row><entry morerows="1">N3‑N2</entry><entry morerows="1">1.382(4)</entry><entry morerows="1">C10‑N2</entry><entry morerows="1">1.408(5)</entry></row><row><entry morerows="1">N5‑N4</entry><entry morerows="1">1.369(5)</entry><entry morerows="1">N10‑C40</entry><entry morerows="1">1.346(5)</entry></row><row><entry morerows="1">N5‑C19</entry><entry morerows="1">1.394(5)</entry><entry morerows="1">N14‑C54</entry><entry morerows="1">1.398(5)</entry></row><row><entry morerows="1">N5‑C25</entry><entry morerows="1">1.464(5)</entry><entry morerows="1">O2‑C8</entry><entry morerows="1">1.317(5)</entry></row><row><entry morerows="1">C46‑C45</entry><entry morerows="1">1.419(5)</entry><entry morerows="1">O2‑C9</entry><entry morerows="1">1.468(5)</entry></row><row><entry morerows="1">C46‑C42</entry><entry morerows="1">1.411(5)</entry><entry morerows="1">C43‑O11</entry><entry morerows="1">1.213(5)</entry></row><row><entry morerows="1">O9‑C27</entry><entry morerows="1">1.323(6)</entry><entry morerows="1">C43‑C42</entry><entry morerows="1">1.479(5)</entry></row><row><entry morerows="1">O9‑C28</entry><entry morerows="1">1.470(7)</entry><entry morerows="1">N9‑C30</entry><entry morerows="1">1.339(5)</entry></row><row><entry morerows="1">C16‑N4</entry><entry morerows="1">1.281(5)</entry><entry morerows="1">N9‑C34</entry><entry morerows="1">1.351(6)</entry></row><row><entry morerows="1">C16‑C12</entry><entry morerows="1">1.532(5)</entry><entry morerows="1">O20‑C62</entry><entry morerows="1">1.318(5)</entry></row><row><entry morerows="1">C16‑C17</entry><entry morerows="1">1.470(6)</entry><entry morerows="1">O20‑C63</entry><entry morerows="1">1.457(7)</entry></row><row><entry morerows="1">C20‑C19</entry><entry morerows="1">1.386(6)</entry><entry morerows="1">O6‑C13</entry><entry morerows="1">1.200(5)</entry></row><row><entry morerows="1">C20‑C21</entry><entry morerows="1">1.386(6)</entry><entry morerows="1">C66‑N18</entry><entry morerows="1">1.333(5)</entry></row><row><entry morerows="1">O16‑C48</entry><entry morerows="1">1.197(5)</entry><entry morerows="1">C66‑C67</entry><entry morerows="1">1.380(6)</entry></row><row><entry morerows="1">O10‑C29</entry><entry morerows="1">1.197(5)</entry><entry morerows="1">N18‑C70</entry><entry morerows="1">1.347(5)</entry></row><row><entry morerows="1">O12‑C43</entry><entry morerows="1">1.305(5)</entry><entry morerows="1">C11‑C12</entry><entry morerows="1">1.503(5)</entry></row><row><entry morerows="1">O12‑C44</entry><entry morerows="1">1.439(5)</entry><entry morerows="1">C11‑C7</entry><entry morerows="1">1.396(5)</entry></row><row><entry morerows="1">O5‑C17</entry><entry morerows="1">1.313(5)</entry><entry morerows="1">N12‑N11</entry><entry morerows="1">1.384(4)</entry></row><row><entry morerows="1">O5‑C18</entry><entry morerows="1">1.459(5)</entry><entry morerows="1">N12‑C42</entry><entry morerows="1">1.333(5)</entry></row><row><entry morerows="1">O7‑C13</entry><entry morerows="1">1.326(5)</entry><entry morerows="1">C26‑C25</entry><entry morerows="1">1.526(6)</entry></row><row><entry morerows="1">O7‑C14</entry><entry morerows="1">1.451(7)</entry><entry morerows="1">C26‑C27</entry><entry morerows="1">1.474(6)</entry></row></tbody></tgroup></table></tables><tables num="0002" id="ctbl0002"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="24%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="24%" /><tbody><row><entry morerows="1">N13‑N14</entry><entry morerows="1">1.364(4)</entry><entry morerows="1">C45‑N11</entry><entry morerows="1">1.403(5)</entry></row><row><entry morerows="1">N13‑C47</entry><entry morerows="1">1.285(5)</entry><entry morerows="1">N1‑C6</entry><entry morerows="1">1.333(5)</entry></row><row><entry morerows="1">N8‑C29</entry><entry morerows="1">1.384(5)</entry><entry morerows="1">N1‑C2</entry><entry morerows="1">1.348(5)</entry></row><row><entry morerows="1">N8‑C30</entry><entry morerows="1">1.412(5)</entry><entry morerows="1">C12‑C13</entry><entry morerows="1">1.539(6)</entry></row><row><entry morerows="1">C10‑C11</entry><entry morerows="1">1.404(6)</entry><entry morerows="1">C12‑C25</entry><entry morerows="1">1.599(5)</entry></row><row><entry morerows="1">C47‑C48</entry><entry morerows="1">1.478(6)</entry><entry morerows="1">O4‑C17</entry><entry morerows="1">1.205(5)</entry></row><row><entry morerows="1">C39‑C40</entry><entry morerows="1">1.367(6)</entry><entry morerows="1">C54‑C55</entry><entry morerows="1">1.382(6)</entry></row><row><entry morerows="1">C39‑C38</entry><entry morerows="1">1.372(7)</entry><entry morerows="1">C57‑C58</entry><entry morerows="1">1.372(6)</entry></row><row><entry morerows="1">N16‑Cu1‑N18</entry><entry morerows="1">80.20(13)</entry><entry morerows="1">N9‑C30‑C31</entry><entry morerows="1">123.9(4)</entry></row><row><entry morerows="1">N16‑Cu1‑N1</entry><entry morerows="1">122.36(13)</entry><entry morerows="1">C31‑C30‑N8</entry><entry morerows="1">121.9(4)</entry></row><row><entry morerows="1">N3‑Cu1‑N16</entry><entry morerows="1">126.80(14)</entry><entry morerows="1">N6‑C23‑C22</entry><entry morerows="1">121.8(5)</entry></row><row><entry morerows="1">N3‑Cu1‑N18</entry><entry morerows="1">123.04(14)</entry><entry morerows="1">N6‑C23‑C24</entry><entry morerows="1">115.4(5)</entry></row><row><entry morerows="1">N3‑Cu1‑N1</entry><entry morerows="1">81.65(13)</entry><entry morerows="1">C22‑C23‑C24</entry><entry morerows="1">122.7(5)</entry></row><row><entry morerows="1">N18‑Cu1‑N1</entry><entry morerows="1">129.42(14)</entry><entry morerows="1">C50‑O15‑C51</entry><entry morerows="1">115.6(4)</entry></row><row><entry morerows="1">N7‑Cu2‑N10</entry><entry morerows="1">122.50(14)</entry><entry morerows="1">C48‑O17‑C49</entry><entry morerows="1">116.4(3)</entry></row><row><entry morerows="1">N7‑Cu2‑N9</entry><entry morerows="1">78.96(13)</entry><entry morerows="1">N14‑C60‑C53</entry><entry morerows="1">102.6(3)</entry></row><row><entry morerows="1">N10‑Cu2‑N9</entry><entry morerows="1">127.89(14)</entry><entry morerows="1">N14‑C60‑C65</entry><entry morerows="1">110.8(3)</entry></row><row><entry morerows="1">N12‑Cu2‑N7</entry><entry morerows="1">125.50(13)</entry><entry morerows="1">N14‑C60‑C61</entry><entry morerows="1">112.8(3)</entry></row><row><entry morerows="1">N12‑Cu2‑N10</entry><entry morerows="1">80.68(13)</entry><entry morerows="1">C65‑C60‑C53</entry><entry morerows="1">118.8(3)</entry></row><row><entry morerows="1">N12‑Cu2‑N9</entry><entry morerows="1">128.06(14)</entry><entry morerows="1">C61‑C60‑C53</entry><entry morerows="1">112.7(3)</entry></row><row><entry morerows="1">C61‑C60‑C65</entry><entry morerows="1">99.5(3)</entry><entry morerows="1">N18‑C70‑C69</entry><entry morerows="1">121.6(4)</entry></row><row><entry morerows="1">C46‑C53‑C60</entry><entry morerows="1">114.1(3)</entry><entry morerows="1">N18‑C70‑C71</entry><entry morerows="1">116.1(4)</entry></row><row><entry morerows="1">C46‑C53‑C50</entry><entry morerows="1">111.1(3)</entry><entry morerows="1">C69‑C70‑C71</entry><entry morerows="1">122.3(4)</entry></row><row><entry morerows="1">C68‑C67‑C66</entry><entry morerows="1">116.9(4)</entry><entry morerows="1">N5‑C25‑C12</entry><entry morerows="1">102.0(3)</entry></row><row><entry morerows="1">C56‑C55‑C54</entry><entry morerows="1">117.0(5)</entry><entry morerows="1">N5‑C25‑C26</entry><entry morerows="1">113.4(3)</entry></row><row><entry morerows="1">C46‑C53‑C47</entry><entry morerows="1">113.3(3)</entry><entry morerows="1">N5‑C25‑C29</entry><entry morerows="1">112.1(3)</entry></row><row><entry morerows="1">C50‑C53‑C60</entry><entry morerows="1">111.8(3)</entry><entry morerows="1">C26‑C25‑C12</entry><entry morerows="1">113.8(3)</entry></row><row><entry morerows="1">C47‑C53‑C60</entry><entry morerows="1">98.6(3)</entry><entry morerows="1">C26‑C25‑C29</entry><entry morerows="1">98.6(3)</entry></row><row><entry morerows="1">C47‑C53‑C50</entry><entry morerows="1">107.2(3)</entry><entry morerows="1">C29‑C25‑C12</entry><entry morerows="1">117.6(3)</entry></row><row><entry morerows="1">C19‑N6‑C23</entry><entry morerows="1">117.7(4)</entry><entry morerows="1">N1‑C6‑N2</entry><entry morerows="1">115.4(4)</entry></row><row><entry morerows="1">N10‑C36‑N11</entry><entry morerows="1">115.0(3)</entry><entry morerows="1">N1‑C6‑C5</entry><entry morerows="1">122.8(4)</entry></row><row><entry morerows="1">N10‑C36‑C37</entry><entry morerows="1">123.5(4)</entry><entry morerows="1">C5‑C6‑N2</entry><entry morerows="1">121.8(4)</entry></row><row><entry morerows="1">C37‑C36‑N11</entry><entry morerows="1">121.4(4)</entry><entry morerows="1">N1‑C2‑C3</entry><entry morerows="1">121.8(5)</entry></row><row><entry morerows="1">N8‑N7‑Cu2</entry><entry morerows="1">112.3(2)</entry><entry morerows="1">N1‑C2‑C1</entry><entry morerows="1">115.4(4)</entry></row><row><entry morerows="1">C26‑N7‑Cu2</entry><entry morerows="1">138.2(3)</entry><entry morerows="1">C3‑C2‑C1</entry><entry morerows="1">122.8(5)</entry></row><row><entry morerows="1">C26‑N7‑N8</entry><entry morerows="1">109.5(3)</entry><entry morerows="1">N2‑N3‑Cu1</entry><entry morerows="1">111.6(2)</entry></row><row><entry morerows="1">N17‑N16‑Cu1</entry><entry morerows="1">111.5(2)</entry><entry morerows="1">N4‑N5‑C19</entry><entry morerows="1">120.7(4)</entry></row><row><entry morerows="1">C61‑N16‑Cu1</entry><entry morerows="1">139.5(3)</entry><entry morerows="1">N4‑N5‑C25</entry><entry morerows="1">113.8(3)</entry></row><row><entry morerows="1">C61‑N16‑N17</entry><entry morerows="1">108.9(3)</entry><entry morerows="1">C19‑N5‑C25</entry><entry morerows="1">125.0(4)</entry></row><row><entry morerows="1">C54‑N15‑C58</entry><entry morerows="1">117.8(4)</entry><entry morerows="1">C45‑C46‑C53</entry><entry morerows="1">123.0(3)</entry></row><row><entry morerows="1">C7‑N3‑Cu1</entry><entry morerows="1">143.5(3)</entry><entry morerows="1">C42‑C46‑C53</entry><entry morerows="1">131.4(3)</entry></row><row><entry morerows="1">C7‑N3‑N2</entry><entry morerows="1">104.3(3)</entry><entry morerows="1">C38‑C37‑C36</entry><entry morerows="1">117.7(5)</entry></row><row><entry morerows="1">C23‑C22‑C21</entry><entry morerows="1">119.6(5)</entry><entry morerows="1">C42‑C46‑C45</entry><entry morerows="1">105.4(3)</entry></row><row><entry morerows="1">C27‑O9‑C28</entry><entry morerows="1">112.2(5)</entry><entry morerows="1">O9‑C27‑C26</entry><entry morerows="1">110.9(5)</entry></row><row><entry morerows="1">N4‑C16‑C12</entry><entry morerows="1">115.5(4)</entry><entry morerows="1">O8‑C27‑O9</entry><entry morerows="1">125.4(5)</entry></row><row><entry morerows="1">N4‑C16‑C17</entry><entry morerows="1">123.6(4)</entry><entry morerows="1">O8‑C27‑C26</entry><entry morerows="1">123.6(5)</entry></row><row><entry morerows="1">C17‑C16‑C12</entry><entry morerows="1">120.2(3)</entry><entry morerows="1">C4‑C3‑C2</entry><entry morerows="1">119.5(5)</entry></row><row><entry morerows="1">C16‑N4‑N5</entry><entry morerows="1">108.8(3)</entry><entry morerows="1">N9‑C34‑C33</entry><entry morerows="1">120.9(5)</entry></row><row><entry morerows="1">C19‑C20‑C21</entry><entry morerows="1">115.8(5)</entry><entry morerows="1">N9‑C34‑C35</entry><entry morerows="1">116.4(4)</entry></row><row><entry morerows="1">C43‑O12‑C44</entry><entry morerows="1">118.8(3)</entry><entry morerows="1">C13‑O7‑C14</entry><entry morerows="1">117.2(4)</entry></row><row><entry morerows="1">C17‑O5‑C18</entry><entry morerows="1">114.8(3)</entry><entry morerows="1">C47‑N13‑N14</entry><entry morerows="1">109.5(3)</entry></row><row><entry morerows="1">N7‑N8‑C30</entry><entry morerows="1">117.5(3)</entry><entry morerows="1">C36‑N10‑Cu2</entry><entry morerows="1">113.8(3)</entry></row><row><entry morerows="1">C29‑N8‑N7</entry><entry morerows="1">111.9(3)</entry><entry morerows="1">C36‑N10‑C40</entry><entry morerows="1">117.1(4)</entry></row><row><entry morerows="1">C29‑N8‑C30</entry><entry morerows="1">128.3(3)</entry><entry morerows="1">C40‑N10‑Cu2</entry><entry morerows="1">129.0(3)</entry></row><row><entry morerows="1">O3‑C10‑C11</entry><entry morerows="1">132.9(4)</entry><entry morerows="1">C33‑C34‑C35</entry><entry morerows="1">122.7(5)</entry></row><row><entry morerows="1">O3‑C10‑N2</entry><entry morerows="1">123.0(4)</entry><entry morerows="1">C22‑C21‑C20</entry><entry morerows="1">120.3(5)</entry></row><row><entry morerows="1">C11‑C10‑N2</entry><entry morerows="1">104.1(3)</entry><entry morerows="1">C55‑C56‑C57</entry><entry morerows="1">119.8(4)</entry></row><row><entry morerows="1">N16‑N17‑C66</entry><entry morerows="1">117.4(3)</entry><entry morerows="1">C65‑N17‑C66</entry><entry morerows="1">128.7(3)</entry></row></tbody></tgroup></table></tables><tables num="0003" id="ctbl0003"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="24%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="24%" /><tbody><row><entry morerows="1">C65‑N17‑N16</entry><entry morerows="1">111.9(3)</entry><entry morerows="1">O15‑C50‑C53</entry><entry morerows="1">111.2(3)</entry></row><row><entry morerows="1">O14‑C50‑O15</entry><entry morerows="1">124.4(4)</entry><entry morerows="1">C54‑N14‑C60</entry><entry morerows="1">122.3(3)</entry></row><row><entry morerows="1">O14‑C50‑C53</entry><entry morerows="1">124.4(4)</entry><entry morerows="1">C8‑O2‑C9</entry><entry morerows="1">117.2(4)</entry></row><row><entry morerows="1">N6‑C19‑N5</entry><entry morerows="1">114.3(4)</entry><entry morerows="1">O12‑C43‑C42</entry><entry morerows="1">113.2(3)</entry></row><row><entry morerows="1">N6‑C19‑C20</entry><entry morerows="1">124.7(4)</entry><entry morerows="1">O11‑C43‑O12</entry><entry morerows="1">124.6(4)</entry></row><row><entry morerows="1">C20‑C19‑N5</entry><entry morerows="1">120.9(4)</entry><entry morerows="1">C67‑C68‑C69</entry><entry morerows="1">120.3(4)</entry></row><row><entry morerows="1">N13‑N14‑C60</entry><entry morerows="1">112.0(3)</entry><entry morerows="1">C32‑C33‑C34</entry><entry morerows="1">120.1(5)</entry></row><row><entry morerows="1">N13‑N14‑C54</entry><entry morerows="1">120.2(3)</entry><entry morerows="1">C4‑C5‑C6</entry><entry morerows="1">117.5(5)</entry></row><row><entry morerows="1">O11‑C43‑C42</entry><entry morerows="1">122.1(4)</entry><entry morerows="1">C37‑C38‑C39</entry><entry morerows="1">120.1(5)</entry></row><row><entry morerows="1">C30‑N9‑Cu2</entry><entry morerows="1">114.8(3)</entry><entry morerows="1">C66‑N18‑C70</entry><entry morerows="1">118.0(3)</entry></row><row><entry morerows="1">C30‑N9‑C34</entry><entry morerows="1">117.6(4)</entry><entry morerows="1">C70‑N18‑Cu1</entry><entry morerows="1">126.8(3)</entry></row><row><entry morerows="1">C34‑N9‑Cu2</entry><entry morerows="1">127.2(3)</entry><entry morerows="1">C10‑C11‑C12</entry><entry morerows="1">122.9(4)</entry></row><row><entry morerows="1">C62‑O20‑C63</entry><entry morerows="1">115.4(5)</entry><entry morerows="1">C7‑C11‑C10</entry><entry morerows="1">106.3(3)</entry></row><row><entry morerows="1">N18‑C66‑N17</entry><entry morerows="1">114.0(3)</entry><entry morerows="1">C3‑C4‑C5</entry><entry morerows="1">120.3(5)</entry></row><row><entry morerows="1">N18‑C66‑C67</entry><entry morerows="1">124.0(4)</entry><entry morerows="1">C66‑N18‑Cu1</entry><entry morerows="1">115.1(3)</entry></row><row><entry morerows="1">C67‑C66‑N17</entry><entry morerows="1">122.0(4)</entry><entry morerows="1">O13‑C45‑C46</entry><entry morerows="1">131.8(4)</entry></row><row><entry morerows="1">C7‑C11‑C12</entry><entry morerows="1">130.6(4)</entry><entry morerows="1">O13‑C45‑N11</entry><entry morerows="1">123.4(4)</entry></row><row><entry morerows="1">N11‑N12‑Cu2</entry><entry morerows="1">111.9(2)</entry><entry morerows="1">N11‑C45‑C46</entry><entry morerows="1">104.8(3)</entry></row><row><entry morerows="1">C42‑N12‑Cu2</entry><entry morerows="1">142.8(3)</entry><entry morerows="1">C6‑N1‑Cu1</entry><entry morerows="1">113.0(3)</entry></row><row><entry morerows="1">C42‑N12‑N11</entry><entry morerows="1">104.7(3)</entry><entry morerows="1">C6‑N1‑C2</entry><entry morerows="1">118.1(4)</entry></row><row><entry morerows="1">N7‑C26‑C25</entry><entry morerows="1">113.6(3)</entry><entry morerows="1">C52‑C51‑O15</entry><entry morerows="1">112.7(8)</entry></row><row><entry morerows="1">N7‑C26‑C27</entry><entry morerows="1">117.1(4)</entry><entry morerows="1">C33‑C32‑C31</entry><entry morerows="1">119.8(5)</entry></row><row><entry morerows="1">C27‑C26‑C25</entry><entry morerows="1">129.2(4)</entry><entry morerows="1">O18‑C65‑C60</entry><entry morerows="1">126.9(4)</entry></row><row><entry morerows="1">C2‑N1‑Cu1</entry><entry morerows="1">128.9(3)</entry><entry morerows="1">O18‑C65‑N17</entry><entry morerows="1">127.2(4)</entry></row><row><entry morerows="1">C16‑C12‑C13</entry><entry morerows="1">106.3(3)</entry><entry morerows="1">N17‑C65‑C60</entry><entry morerows="1">105.9(3)</entry></row><row><entry morerows="1">C16‑C12‑C25</entry><entry morerows="1">98.9(3)</entry><entry morerows="1">N15‑C54‑N14</entry><entry morerows="1">113.2(3)</entry></row><row><entry morerows="1">C11‑C12‑C16</entry><entry morerows="1">112.1(3)</entry><entry morerows="1">N15‑C54‑C55</entry><entry morerows="1">124.2(4)</entry></row><row><entry morerows="1">C11‑C12‑C13</entry><entry morerows="1">112.1(3)</entry><entry morerows="1">C55‑C54‑N14</entry><entry morerows="1">122.6(4)</entry></row><row><entry morerows="1">C11‑C12‑C25</entry><entry morerows="1">114.2(3)</entry><entry morerows="1">O5‑C17‑C16</entry><entry morerows="1">114.4(3)</entry></row><row><entry morerows="1">C13‑C12‑C25</entry><entry morerows="1">112.4(3)</entry><entry morerows="1">O4‑C17‑C16</entry><entry morerows="1">120.5(4)</entry></row><row><entry morerows="1">N13‑C47‑C53</entry><entry morerows="1">114.7(3)</entry><entry morerows="1">O4‑C17‑O5</entry><entry morerows="1">125.1(4)</entry></row><row><entry morerows="1">N13‑C47‑C48</entry><entry morerows="1">119.0(4)</entry><entry morerows="1">N3‑C7‑C11</entry><entry morerows="1">113.1(4)</entry></row><row><entry morerows="1">C48‑C47‑C53</entry><entry morerows="1">126.1(4)</entry><entry morerows="1">N3‑C7‑C8</entry><entry morerows="1">115.9(4)</entry></row><row><entry morerows="1">C40‑C39‑C38</entry><entry morerows="1">119.0(4)</entry><entry morerows="1">C64‑C63‑O20</entry><entry morerows="1">106.7(9)</entry></row><row><entry morerows="1">C58‑C57‑C56</entry><entry morerows="1">118.6(4)</entry><entry morerows="1">C32‑C31‑C30</entry><entry morerows="1">117.6(4)</entry></row><row><entry morerows="1">C11‑C7‑C8</entry><entry morerows="1">130.9(4)</entry><entry morerows="1">O19‑C62‑O20</entry><entry morerows="1">126.3(4)</entry></row><row><entry morerows="1">O19‑C62‑C61</entry><entry morerows="1">121.9(4)</entry><entry morerows="1">C15‑C14‑O7</entry><entry morerows="1">120.9(11)</entry></row><row><entry morerows="1">O20‑C62‑C61</entry><entry morerows="1">111.8(4)</entry><entry morerows="1">C46‑C42‑C43</entry><entry morerows="1">130.7(4)</entry></row><row><entry morerows="1">N16‑C61‑C60</entry><entry morerows="1">113.8(3)</entry><entry morerows="1">N12‑C42‑C46</entry><entry morerows="1">113.0(3)</entry></row><row><entry morerows="1">N16‑C61‑C62</entry><entry morerows="1">121.0(4)</entry><entry morerows="1">N12‑C42‑C43</entry><entry morerows="1">116.2(3)</entry></row><row><entry morerows="1">C62‑C61‑C60</entry><entry morerows="1">124.6(3)</entry><entry morerows="1">N3‑N2‑C10</entry><entry morerows="1">112.2(3)</entry></row><row><entry morerows="1">N15‑C58‑C57</entry><entry morerows="1">122.6(4)</entry><entry morerows="1">N3‑N2‑C6</entry><entry morerows="1">117.8(3)</entry></row><row><entry morerows="1">N15‑C58‑C59</entry><entry morerows="1">115.7(4)</entry><entry morerows="1">C10‑N2‑C6</entry><entry morerows="1">130.0(4)</entry></row><row><entry morerows="1">C57‑C58‑C59</entry><entry morerows="1">121.7(4)</entry><entry morerows="1">C70‑C69‑C68</entry><entry morerows="1">119.2(4)</entry></row><row><entry morerows="1">N12‑N11‑C36</entry><entry morerows="1">117.7(3)</entry><entry morerows="1">C45‑N11‑C36</entry><entry morerows="1">130.1(3)</entry></row><row><entry morerows="1">N12‑N11‑C45</entry><entry morerows="1">112.2(3)</entry><entry morerows="1">O17‑C48‑C47</entry><entry morerows="1">110.4(3)</entry></row><row><entry morerows="1">O16‑C48‑O17</entry><entry morerows="1">125.2(4)</entry><entry morerows="1">N8‑C29‑C25</entry><entry morerows="1">106.4(3)</entry></row><row><entry morerows="1">O16‑C48‑C47</entry><entry morerows="1">124.4(4)</entry><entry morerows="1">O7‑C13‑C12</entry><entry morerows="1">110.9(4)</entry></row><row><entry morerows="1">O2‑C8‑C7</entry><entry morerows="1">112.3(4)</entry><entry morerows="1">O6‑C13‑O7</entry><entry morerows="1">124.1(4)</entry></row><row><entry morerows="1">O1‑C8‑O2</entry><entry morerows="1">124.8(4)</entry><entry morerows="1">O6‑C13‑C12</entry><entry morerows="1">125.0(4)</entry></row><row><entry morerows="1">O1‑C8‑C7</entry><entry morerows="1">122.9(4)</entry><entry morerows="1">N10‑C40‑C41</entry><entry morerows="1">116.0(4)</entry></row><row><entry morerows="1">O10‑C29‑N8</entry><entry morerows="1">126.1(4)</entry><entry morerows="1">C39‑C40‑C41</entry><entry morerows="1">121.4(4)</entry></row><row><entry morerows="1">O10‑C29‑C25</entry><entry morerows="1">127.5(4)</entry><entry morerows="1">N9‑C30‑N8</entry><entry morerows="1">114.1(3)</entry></row><row><entry morerows="1">N10‑C40‑C39</entry><entry morerows="1">122.6(4)</entry><entry morerows="1"> </entry><entry morerows="1"> </entry></row></tbody></tgroup></table></tables>。 |
