发明名称 |
PRODUCTION METHOD FOR COMPOUND COMPRISING AMINO GROUP AND/OR HYDROXYL GROUP |
摘要 |
Disclosed is a method for producing a compound having an amino group and/or a hydroxyl group from a substrate compound having an atomic group containing CO or CS by eliminating such atomic group. The substrate compound, having an atomic group containing CO or CS (for example, an amide, a carbamate, or the like), is allowed to react with a compound expressed by formula (I) below, at a temperature of 120° C. or lower, preferably in the presence of an ammonium salt, to eliminate such atomic group containing CO or CS. In formula (I) A may not be present, and in a case where A is present, A represents an alkyl group having 1 to 6 carbon atoms. H2N-A—NH2 (I) - - -. |
申请公布号 |
US2015105559(A1) |
申请公布日期 |
2015.04.16 |
申请号 |
US201314382455 |
申请日期 |
2013.03.04 |
申请人 |
KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION |
发明人 |
Ohshima Takashi;Morimoto Hiroyuki;Shimizu Yuhei |
分类号 |
C07C209/62;C07C213/02;C07C227/04;C07D309/12;C07D209/08;C07D217/02;C07D317/28;C07C29/00;C07C41/18;C07D209/16;C07F7/18 |
主分类号 |
C07C209/62 |
代理机构 |
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代理人 |
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主权项 |
1. A method for producing a compound having an amino group and/or a hydroxyl group from a substrate having an atomic group containing CX, where X represents an oxygen atom or a sulfur atom, which comprises allowing said substrate compound to react with a compound expressed by formula (I) below in the presence of an ammonium salt at a temperature of 120° C. or lower to eliminate said atomic group containing the CX from said substrate compound:
H2N-A—NH2 (I)wherein A may not be present, and in a case where A is not present, formula (I) is hydrazine, and in a case where A is present, A represents an alkyl group having 1 to 6 carbon atoms and the formula (I) represents an alkylamine having said alkyl group in which one or two of the carbon atoms may be substituted with nitrogen atom(s). |
地址 |
Fukuoka JP |