| 摘要 |
The present invention provides an electrolytic solution for a nonaqueous electrolyte battery and a nonaqueous electrolyte battery having excellent cycle characteristics and high-temperature storage characteristics without causing hydrolysis of a fluorine-containing lithium salt, such as LiPF 6 , contained as a solute and containing a less amount of free fluorine ions, as well as a method of producing the electrolytic solution for a nonaqueous electrolyte battery. The electrolytic solution for a nonaqueous battery of the present invention includes a nonaqueous solvent and at least one fluorine-containing lithium salt as a solute and further includes an oxalato salt represented by Formula (1), wherein the content of a hexafluoro salt represented by Formula (2) is 150 mass ppm or less,
€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒLi x MF (6-2y) (C 2 O 4 ) y €ƒ€ƒ€ƒ€ƒ€ƒ(1)
€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒLi x MF 6 €ƒ€ƒ€ƒ€ƒ€ƒ(2)
wherein M represents Fe, Sn, Si, Ge or Ti; x is 3 when M is Fe, and 2 when M is Sn, Si, Ge or Ti; and y is an integer of 1 to 3, wherein the content of the oxalato salt is 6500 mass ppm or less and the content of free fluorine ions is 50 mass ppm or less. |
