发明名称 Organic electroluminescence devices containing substituted benzo[C]phenanthrenes
摘要 The present invention relates to substituted benzo[c]phenanthrene derivatives and to the production and to the use thereof in electronic devices, and to the electronic devices themselves. The present invention relates in particular an electronic device containing 10-benzo[c]phenanthrene derivatives of, e.g., formula (II); substituted with at least one aromatic unit or at least one diarylamino unit.
申请公布号 US9006503(B2) 申请公布日期 2015.04.14
申请号 US201414146106 申请日期 2014.01.02
申请人 Merck Patent GmbH 发明人 Parham Amir Hossain;Buesing Arne;Heil Holger;Stoessel Philipp
分类号 C07C13/62;H01L51/00;C09K11/06;H05B33/14;C09B57/00;C09B1/00;C09B3/02;C09B3/78 主分类号 C07C13/62
代理机构 Drinker Biddle & Reath LLP 代理人 Drinker Biddle & Reath LLP
主权项 1. An electronic device comprising at least one compound of formula (II):wherein R2 is selected from the group consisting of Ar and N(Ar)2; Ar is on each occurrence, identically or differently, an aromatic or heteroaromatic ring system having 5 to 40 aromatic ring atoms, which are optionally substituted by one or more radicals R13, where, in the case where two Ar are bonded to the same N or P atom, the two Ar may be linked to one another by a single covalent bond or a divalent group selected from the group consisting of BR13, C(R13)2, Si(R13)2, C═O, C═NR13, C═C(R13)2, O, S, S═O, SO2, NR13, PR13 and P(═O)R13;with the proviso that Ar, if it is bonded directly to the aromatic skeleton of the formula (II), is different from triarylamine;R1 and R12 are H;R13 is identical or different on each occurrence and is selected from the group consisting of H, D, F, Cl, Br, I, CHO, N(R14)2, CN, NO2, Si(R14)3, B(OR14)2, OSO2R14, straight-chain alkyl, alkenyl, alkoxy and thioalkoxy groups having 1 to 40 C atoms and branched, monocyclic or polycyclic alkyl, alkenyl, alkoxy and thioalkoxy groups having 3 to 40 C atoms, each of which are optionally substituted by one or more radicals R14, where one or more non-adjacent CH2 groups are optionally replaced by R14C═CR14, C≡C, Si(R14)2, Ge(R14)2, Sn(R14)2, C═O, C═S, C═Se, C═NR14, P(═O)(R14), SO, SO2, NR14, O, S or CONR14 and where one or more H atoms are optionally replaced by D, F, Cl, Br, I, CN or NO2, and aromatic or heteroaromatic ring systems having 5 to 40 aromatic ring atoms, which in each case are optionally substituted by one or more radicals R14, and aryloxy or heteroaryloxy groups having 5 to 40 aromatic ring atoms which are optionally substituted by one or more radicals R14, and a combination of these systems, where two or more adjacent substituents R13 optionally define a monocyclic or polycyclic, aliphatic or aromatic ring system with one another;R14 is identical or different on each occurrence and is selected from the group consisting of H and an aliphatic hydrocarbon radical having 1 to 20 carbon atoms, where one or more H atoms of the aliphatic hydrocarbon radical are optionally replaced by F; where, in the case where two or more substituents R14 are adjacent, these optionally define a monocyclic or polycyclic aliphatic ring system; with the proviso that the following compounds are excluded:
地址 Darmstadt DE