发明名称 Positive electrode active materials for lithium secondary battery, method for preparing the same and lithium secondary battery comprising the same
摘要 A positive electrode active material for a lithium secondary battery, the material represented by the formulas: LiNi(1-x-y)CoxAlyO2 or LiNi(1-x-y)CoxMnyO2 (0.1<x≦0.15 and 0.03<y<0.1), and whose X-ray diffraction peak intensity ratio 1(2θ=45 degrees)/I(2θ=18 degrees) of an X-ray diffraction peak intensities found in the vicinity of an X-ray diffraction-scanning angle 2θ of about 45 degrees, to an X-ray diffraction peak intensity found in the vicinity of an X-ray diffraction-scanning angle 2θ of about 18 degrees, is in the range of from 46% to 51%. The positive electrode active material is fabricated by mixing Ni(1-x-y)CoxAlyO2 or Ni(1-x-y)CoxMnyO2 (0.1<x≦0.15 and 0.03<y<0.1) with lithium hydrates (LiOH.H2O); and calcinating the mixture at a temperature of 750° C., for more than 30 hrs, under an oxygen atmosphere.
申请公布号 US8999578(B2) 申请公布日期 2015.04.07
申请号 US200812173334 申请日期 2008.07.15
申请人 Samsung SDI Co., Ltd. 发明人 Park Jungjoon;Song Suho
分类号 H01M4/131;H01M4/1391;H01M4/525;H01M10/0525;C01G51/00;C01G53/00;H01M4/505 主分类号 H01M4/131
代理机构 Christie, Parker &amp; Hale, LLP 代理人 Christie, Parker &amp; Hale, LLP
主权项 1. A positive electrode active material for a lithium secondary battery, comprising a lithiated metal oxide represented by the formula LiNi(1-x-y)CoxAlyO2, where 0.1<x≦0.15 and 0.03<y<0.1, wherein the lithiated metal oxide has an X-ray diffraction peak intensity ratio of an X-ray diffraction peak intensity found in the vicinity of an X-ray diffraction-scanning angle 2θ of about 45 degrees to an X-ray diffraction peak intensity found in the vicinity of an X-ray diffraction-scanning angle 2θ of about 18 degrees (I(2θ=45 degrees)/I(2θ=18))degrees) in the range of from 47.8% to 49.6%; and the lithiated metal oxide is formed by calcinating a lithiated metal oxide precursor at a temperature of about 750° C. to 900° C. for about 29 to about 40 hours.
地址 Yongsin-si KR