Making epoxidized esters from epoxidized natural fats and oils

摘要

Processes are described for making epoxidized fatty acid esters from epoxidized natural fats and oils, wherein low moisture fats and oils are identified and selected or made and used in a transesterification process. The products undergo phase separation, and reduced molar excesses of alcohol may be employed compared to processes not employing a low moisture feedstock.

主权项

1. A process for making an epoxidized fatty acid ester from an epoxidized natural fat or oil, comprising:
determining the moisture content of one or more epoxidized natural fats or oils; selecting a low moisture epoxidized natural fat or oil for use; transesterifying the selected low moisture natural fat or oil with an anhydrous alcohol in the presence of a transesterification catalyst selected from the group consisting of sodium methoxide, sodium ethoxide, potassium methoxide, potassium ethoxide, potassium tert-butoxide or an N-heterocyclic carbene catalyst and under conditions which are effective for carrying out the transesterification reaction; allowing the products of the transesterification reaction to phase-separate into a byproduct glycerol-containing phase and epoxidized fatty acid ester-containing phase; and recovering the epoxidized fatty acid ester-containing phase, under the circumstance that the above process steps are carried out in the substantial absence of moisture from other sources than the selected low moisture epoxidized natural fat or oil.