Combined heavy reformate dealkylation-transalkylation process for maximizing xylenes production

摘要

A method of forming mixed xylenes from a heavy reformate using a dealkylation-transalkylation system includes the step of introducing both a heavy reformate containing methyl ethyl benzenes and tri-methyl benzenes and that is sufficiently free of toluene and a hydrogen-containing material into the dealkylation stage such that the heavy reformate and the hydrogen-containing material intermingle and contact the hydrodealkylation catalyst. The dealkylation-transalkylation system includes dealkylation, non-aromatic product gas separations and transalkylation stages. Toluene forms from the reaction of methyl ethyl benzenes and hydrogen in the presence of the hydrodealkylation catalyst. The method also includes the step of introducing a dealkylated heavy reformate into the transalkylation stage such that the dealkylated heavy reformate contacts a transalkylation catalyst, forming a transalkylation stage product mixture includes mixed xylenes.

主权项

1. A method of forming mixed xylenes from a heavy reformate using a dealkylation-transalkylation system, the method comprising the steps of:
introducing both the heavy reformate and a hydrogen-containing material into a dealkylation stage of the dealkylation-transalkylation system such that the heavy reformate and the hydrogen-containing material intermingle and contact a hydrodealkylation catalyst, where the dealkylation stage contains the hydrodealkylation catalyst, where the heavy reformate comprises a significant amount of both methyl ethyl benzenes and tri-methyl benzenes and is substantially free of toluene by weight, and where the hydrogen-containing material comprises hydrogen; operating the dealkylation stage such that toluene forms from the reaction methyl ethyl benzenes and hydrogen in the presence of the hydrodealkylation catalyst and such that a dealkylation stage product is produced, where the dealkylation stage product comprises toluene, tri-methyl benzenes and non-aromatic product gas; operating the non-aromatic product gas separations stage such that the non-aromatic product gas and a dealkylation heavy reformate are produced separately and the non-aromatic product gas from the dealkylation stage product is removed before it is introduced into the vessel where transalkylation occurs, where the dealkylation heavy reformate comprises toluene and tri-methyl benzenes; introducing the dealkylated heavy reformate into the transalkylation stage such that the dealkylated heavy reformate contacts a transalkylation catalyst, where the transalkylation stage contains the transalkylation catalyst; and operating the transalkylation stage such that mixed xylenes form from reaction of tri-methyl benzenes and toluene in the presence of the transalkylation catalyst and such that a transalkylation stage product is produced, where the transalkylation stage product mixture comprises xylenes.