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一种配合物[Cu<sub>2</sub>(L<sup>7</sup>)(L<sup>10</sup>)]，其特征在于配合物[Cu<sub>2</sub>(L<sup>7</sup>)(L<sup>10</sup>)]的分子式为：C<sub>67</sub>H<sub>52</sub>Cu<sub>2</sub>N<sub>18</sub>O<sub>20</sub>Cl<sub>6</sub>，分子量为：1769.07，H<sub>2</sub>L<sup>7</sup>＝(4S)‑3,6‑二甲基4‑丙基1,8‑二(6‑氯吡啶)‑4‑(2‑(6‑氯吡啶)‑5‑(甲酯基)‑3‑氧‑2,3‑二氢‑1‑氢‑吡唑)‑9‑氧‑1,2,7,8‑四氮杂螺[4.4]壬‑6‑烯‑3,4,6‑三甲酸甲酯；H<sub>2</sub>L<sup>10</sup>＝(4S)‑4‑丁基3,6‑二甲基1,8‑二(6‑氯吡啶)‑4‑(2‑(6‑氯吡啶)‑5‑(甲酯基)‑3‑氧‑2,3‑二氢‑1‑氢‑吡唑)‑9‑氧‑1,2,7,8‑四氮杂螺[4.4]壬‑6‑烯‑3,4,6‑三甲酸甲酯，晶体结构参数表见表一，键长键角数据见表二；具有良好的抗肿瘤活性；所述配合物[Cu<sub>2</sub>(L<sup>7</sup>)(L<sup>10</sup>)]的原位合成方法具体步骤为：(1)将0.05‑0.15克分析纯5‑乙酸‑1‑(6‑氯吡啶)‑1‑氢‑吡唑‑3‑甲酸甲酯和0.05‑0.15克分析纯三水硝酸铜溶于10‑20毫升体积比为1：1的无水乙腈和分析纯正丁醇的混合溶液中；(2)将步骤(1)所制得的溶液转入聚四氟乙烯的反应釜中，在80‑90℃下反应60‑80小时，降温至室温，过滤，滤液置于室温下自然挥发结晶，10天后得到单晶级[Cu<sub>2</sub>(L<sup>7</sup>)(L<sup>10</sup>)]配合物，其晶体学参数见表一，键长键角数据见表二；表一：[Cu<sub>2</sub>(L<sup>7</sup>)(L<sup>10</sup>)]的晶体学参数<img file="FDA0000638962570000011.GIF" wi="1339" he="1477" />表二：[Cu<sub>2</sub>(L<sup>7</sup>)(L<sup>10</sup>)]的键长<img file="FDA0000638962570000012.GIF" wi="82" he="90" />和键角(°)<tables num="0001" id="ctbl0001"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="23%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="25%" /><tbody><row><entry morerows="1">Cu1‑N3</entry><entry morerows="1">1.977(4)</entry><entry morerows="1">C9‑C10</entry><entry morerows="1">1.416(6)</entry></row></tbody></tgroup></table></tables><tables num="0002" id="ctbl0002"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="23%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="25%" /><tbody><row><entry morerows="1">Cu1‑N18</entry><entry morerows="1">2.075(4)</entry><entry morerows="1">O16‑C51</entry><entry morerows="1">1.181(7)</entry></row><row><entry morerows="1">Cu1‑N1</entry><entry morerows="1">2.044(4)</entry><entry morerows="1">C63‑C64</entry><entry morerows="1">1.394(6)</entry></row><row><entry morerows="1">Cu1‑N16</entry><entry morerows="1">2.001(4)</entry><entry morerows="1">C10‑C6</entry><entry morerows="1">1.398(6)</entry></row><row><entry morerows="1">Cu2‑N12</entry><entry morerows="1">1.994(4)</entry><entry morerows="1">C10‑C11</entry><entry morerows="1">1.490(6)</entry></row><row><entry morerows="1">Cu2‑N7</entry><entry morerows="1">2.018(4)</entry><entry morerows="1">N5‑C24</entry><entry morerows="1">1.472(5)</entry></row><row><entry morerows="1">Cu2‑N10</entry><entry morerows="1">2.042(4)</entry><entry morerows="1">N5‑C19</entry><entry morerows="1">1.381(7)</entry></row><row><entry morerows="1">Cu2‑N9</entry><entry morerows="1">2.057(4)</entry><entry morerows="1">C6‑C7</entry><entry morerows="1">1.482(6)</entry></row><row><entry morerows="1">Cl4‑C34</entry><entry morerows="1">1.716(6)</entry><entry morerows="1">C39‑C40</entry><entry morerows="1">1.491(6)</entry></row><row><entry morerows="1">Cl6‑C67</entry><entry morerows="1">1.717(6)</entry><entry morerows="1">C39‑C43</entry><entry morerows="1">1.395(6)</entry></row><row><entry morerows="1">Cl1‑C1</entry><entry morerows="1">1.720(6)</entry><entry morerows="1">O17‑C51</entry><entry morerows="1">1.336(7)</entry></row><row><entry morerows="1">Cl3‑C33</entry><entry morerows="1">1.724(7)</entry><entry morerows="1">O17‑C52</entry><entry morerows="1">1.426(9)</entry></row><row><entry morerows="1">Cl2‑C23</entry><entry morerows="1">1.741(8)</entry><entry morerows="1">C16‑C11</entry><entry morerows="1">1.531(6)</entry></row><row><entry morerows="1">Cl5‑C57</entry><entry morerows="1">1.727(8)</entry><entry morerows="1">C16‑C17</entry><entry morerows="1">1.467(7)</entry></row><row><entry morerows="1">N3‑N2</entry><entry morerows="1">1.385(5)</entry><entry morerows="1">N14‑N13</entry><entry morerows="1">1.363(6)</entry></row><row><entry morerows="1">N3‑C6</entry><entry morerows="1">1.333(6)</entry><entry morerows="1">N14‑C58</entry><entry morerows="1">1.461(6)</entry></row><row><entry morerows="1">O3‑C9</entry><entry morerows="1">1.242(5)</entry><entry morerows="1">N14‑C53</entry><entry morerows="1">1.390(7)</entry></row><row><entry morerows="1">O2‑C7</entry><entry morerows="1">1.331(5)</entry><entry morerows="1">C62‑C58</entry><entry morerows="1">1.534(7)</entry></row><row><entry morerows="1">O2‑C8</entry><entry morerows="1">1.459(6)</entry><entry morerows="1">C59‑C58</entry><entry morerows="1">1.522(6)</entry></row><row><entry morerows="1">O18‑C62</entry><entry morerows="1">1.204(5)</entry><entry morerows="1">C59‑C60</entry><entry morerows="1">1.496(7)</entry></row><row><entry morerows="1">O4‑C12</entry><entry morerows="1">1.190(6)</entry><entry morerows="1">N6‑C19</entry><entry morerows="1">1.318(7)</entry></row><row><entry morerows="1">O10‑C25</entry><entry morerows="1">1.186(6)</entry><entry morerows="1">N6‑C23</entry><entry morerows="1">1.316(7)</entry></row><row><entry morerows="1">O7‑C17</entry><entry morerows="1">1.319(6)</entry><entry morerows="1">C11‑C24</entry><entry morerows="1">1.600(6)</entry></row><row><entry morerows="1">O7‑C18</entry><entry morerows="1">1.433(8)</entry><entry morerows="1">C11‑C12</entry><entry morerows="1">1.558(7)</entry></row><row><entry morerows="1">N17‑N16</entry><entry morerows="1">1.394(5)</entry><entry morerows="1">C24‑C26</entry><entry morerows="1">1.502(6)</entry></row><row><entry morerows="1">N17‑C63</entry><entry morerows="1">1.399(6)</entry><entry morerows="1">C24‑C25</entry><entry morerows="1">1.551(7)</entry></row><row><entry morerows="1">N17‑C62</entry><entry morerows="1">1.390(6)</entry><entry morerows="1">C27‑C26</entry><entry morerows="1">1.488(7)</entry></row><row><entry morerows="1">O11‑C40</entry><entry morerows="1">1.194(5)</entry><entry morerows="1">C5‑C4</entry><entry morerows="1">1.394(7)</entry></row><row><entry morerows="1">N12‑N11</entry><entry morerows="1">1.372(5)</entry><entry morerows="1">N13‑C50</entry><entry morerows="1">1.280(7)</entry></row><row><entry morerows="1">N12‑C39</entry><entry morerows="1">1.333(5)</entry><entry morerows="1">C44‑C43</entry><entry morerows="1">1.511(6)</entry></row><row><entry morerows="1">O8‑C27</entry><entry morerows="1">1.197(6)</entry><entry morerows="1">C44‑C58</entry><entry morerows="1">1.593(7)</entry></row><row><entry morerows="1">N18‑C63</entry><entry morerows="1">1.321(6)</entry><entry morerows="1">C44‑C45</entry><entry morerows="1">1.547(7)</entry></row><row><entry morerows="1">N18‑C67</entry><entry morerows="1">1.338(6)</entry><entry morerows="1">C44‑C50</entry><entry morerows="1">1.533(7)</entry></row><row><entry morerows="1">N1‑C5</entry><entry morerows="1">1.338(6)</entry><entry morerows="1">C43‑C42</entry><entry morerows="1">1.420(6)</entry></row><row><entry morerows="1">N1‑C1</entry><entry morerows="1">1.330(7)</entry><entry morerows="1">C29‑C30</entry><entry morerows="1">1.383(8)</entry></row><row><entry morerows="1">N2‑C9</entry><entry morerows="1">1.415(6)</entry><entry morerows="1">C64‑C65</entry><entry morerows="1">1.386(8)</entry></row><row><entry morerows="1">N2‑C5</entry><entry morerows="1">1.384(6)</entry><entry morerows="1">N15‑C53</entry><entry morerows="1">1.344(8)</entry></row><row><entry morerows="1">O12‑C40</entry><entry morerows="1">1.326(6)</entry><entry morerows="1">N15‑C57</entry><entry morerows="1">1.318(8)</entry></row><row><entry morerows="1">O12‑C41</entry><entry morerows="1">1.443(6)</entry><entry morerows="1">C50‑C51</entry><entry morerows="1">1.486(8)</entry></row><row><entry morerows="1">N16‑C59</entry><entry morerows="1">1.276(6)</entry><entry morerows="1">C38‑C37</entry><entry morerows="1">1.378(8)</entry></row><row><entry morerows="1">N7‑N8</entry><entry morerows="1">1.396(5)</entry><entry morerows="1">C65‑C66</entry><entry morerows="1">1.350(8)</entry></row><row><entry morerows="1">N7‑C26</entry><entry morerows="1">1.282(6)</entry><entry morerows="1">C67‑C66</entry><entry morerows="1">1.370(8)</entry></row><row><entry morerows="1">O15‑C45</entry><entry morerows="1">1.330(6)</entry><entry morerows="1">C34‑C35</entry><entry morerows="1">1.357(9)</entry></row><row><entry morerows="1">O15‑C46</entry><entry morerows="1">1.453(7)</entry><entry morerows="1">C46‑C47</entry><entry morerows="1">1.519(11)</entry></row><row><entry morerows="1">O1‑C7</entry><entry morerows="1">1.193(6)</entry><entry morerows="1">C1‑C2</entry><entry morerows="1">1.369(8)</entry></row><row><entry morerows="1">N10‑C38</entry><entry morerows="1">1.336(7)</entry><entry morerows="1">C32‑C33</entry><entry morerows="1">1.361(10)</entry></row><row><entry morerows="1">N10‑C34</entry><entry morerows="1">1.344(6)</entry><entry morerows="1">C32‑C31</entry><entry morerows="1">1.358(11)</entry></row><row><entry morerows="1">O13‑C42</entry><entry morerows="1">1.244(6)</entry><entry morerows="1">C30‑C31</entry><entry morerows="1">1.375(9)</entry></row><row><entry morerows="1">O5‑C12</entry><entry morerows="1">1.320(6)</entry><entry morerows="1">C4‑C3</entry><entry morerows="1">1.369(9)</entry></row><row><entry morerows="1">O5‑C13</entry><entry morerows="1">1.448(6)</entry><entry morerows="1">C19‑C20</entry><entry morerows="1">1.388(9)</entry></row><row><entry morerows="1">O14‑C45</entry><entry morerows="1">1.193(6)</entry><entry morerows="1">C13‑C14</entry><entry morerows="1">1.466(11)</entry></row><row><entry morerows="1">N8‑C25</entry><entry morerows="1">1.388(6)</entry><entry morerows="1">C35‑C36</entry><entry morerows="1">1.379(10)</entry></row><row><entry morerows="1">N8‑C29</entry><entry morerows="1">1.409(6)</entry><entry morerows="1">C2‑C3</entry><entry morerows="1">1.384(9)</entry></row><row><entry morerows="1">O9‑C27</entry><entry morerows="1">1.307(6)</entry><entry morerows="1">C53‑C54</entry><entry morerows="1">1.373(9)</entry></row><row><entry morerows="1">O9‑C28</entry><entry morerows="1">1.452(7)</entry><entry morerows="1">C57‑C56</entry><entry morerows="1">1.358(10)</entry></row><row><entry morerows="1">O6‑C17</entry><entry morerows="1">1.205(6)</entry><entry morerows="1">C36‑C37</entry><entry morerows="1">1.378(9)</entry></row><row><entry morerows="1">N9‑C29</entry><entry morerows="1">1.326(7)</entry><entry morerows="1">C23‑C22</entry><entry morerows="1">1.339(11)</entry></row><row><entry morerows="1">N9‑C33</entry><entry morerows="1">1.338(7)</entry><entry morerows="1">C54‑C55</entry><entry morerows="1">1.394(12)</entry></row><row><entry morerows="1">N11‑C42</entry><entry morerows="1">1.408(6)</entry><entry morerows="1">C56‑C55</entry><entry morerows="1">1.338(13)</entry></row></tbody></tgroup></table></tables><tables num="0003" id="ctbl0003"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="23%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="25%" /><tbody><row><entry morerows="1">N11‑C38</entry><entry morerows="1">1.405(6)</entry><entry morerows="1">C47‑C48</entry><entry morerows="1">1.559(13)</entry></row><row><entry morerows="1">O20‑C60</entry><entry morerows="1">1.322(7)</entry><entry morerows="1">C20‑C21</entry><entry morerows="1">1.409(12)</entry></row><row><entry morerows="1">O20‑C61</entry><entry morerows="1">1.465(8)</entry><entry morerows="1">C21‑C22</entry><entry morerows="1">1.346(14)</entry></row><row><entry morerows="1">O19‑C60</entry><entry morerows="1">1.190(7)</entry><entry morerows="1">C14‑C15</entry><entry morerows="1">1.51(2)</entry></row><row><entry morerows="1">N4‑N5</entry><entry morerows="1">1.362(6)</entry><entry morerows="1">C48‑C49</entry><entry morerows="1">1.436(15)</entry></row><row><entry morerows="1">N4‑C16</entry><entry morerows="1">1.282(6)</entry><entry morerows="1"> </entry><entry morerows="1"> </entry></row><row><entry morerows="1">N3‑Cu1‑N18</entry><entry morerows="1">119.01(16)</entry><entry morerows="1">C25‑C24‑C11</entry><entry morerows="1">117.6(4)</entry></row><row><entry morerows="1">N3‑Cu1‑N1</entry><entry morerows="1">80.21(15)</entry><entry morerows="1">O8‑C27‑O9</entry><entry morerows="1">126.3(5)</entry></row><row><entry morerows="1">N3‑Cu1‑N16</entry><entry morerows="1">130.30(15)</entry><entry morerows="1">O8‑C27‑C26</entry><entry morerows="1">121.1(5)</entry></row><row><entry morerows="1">N1‑Cu1‑N18</entry><entry morerows="1">135.80(16)</entry><entry morerows="1">O9‑C27‑C26</entry><entry morerows="1">112.6(4)</entry></row><row><entry morerows="1">N16‑Cu1‑N18</entry><entry morerows="1">78.79(15)</entry><entry morerows="1">N1‑C5‑N2</entry><entry morerows="1">114.6(4)</entry></row><row><entry morerows="1">N16‑Cu1‑N1</entry><entry morerows="1">120.76(16)</entry><entry morerows="1">N1‑C5‑C4</entry><entry morerows="1">122.4(5)</entry></row><row><entry morerows="1">N12‑Cu2‑N7</entry><entry morerows="1">130.26(16)</entry><entry morerows="1">N2‑C5‑C4</entry><entry morerows="1">123.1(4)</entry></row><row><entry morerows="1">N12‑Cu2‑N10</entry><entry morerows="1">80.41(16)</entry><entry morerows="1">C50‑N13‑N14</entry><entry morerows="1">108.7(4)</entry></row><row><entry morerows="1">N12‑Cu2‑N9</entry><entry morerows="1">118.57(16)</entry><entry morerows="1">C43‑C44‑C58</entry><entry morerows="1">113.0(4)</entry></row><row><entry morerows="1">N7‑Cu2‑N10</entry><entry morerows="1">120.90(16)</entry><entry morerows="1">C43‑C44‑C45</entry><entry morerows="1">112.7(4)</entry></row><row><entry morerows="1">N7‑Cu2‑N9</entry><entry morerows="1">79.11(16)</entry><entry morerows="1">C43‑C44‑C50</entry><entry morerows="1">113.6(4)</entry></row><row><entry morerows="1">N10‑Cu2‑N9</entry><entry morerows="1">135.49(16)</entry><entry morerows="1">C45‑C44‑C58</entry><entry morerows="1">110.7(4)</entry></row><row><entry morerows="1">N2‑N3‑Cu1</entry><entry morerows="1">112.6(3)</entry><entry morerows="1">C50‑C44‑C58</entry><entry morerows="1">99.0(4)</entry></row><row><entry morerows="1">C6‑N3‑Cu1</entry><entry morerows="1">142.1(3)</entry><entry morerows="1">C50‑C44‑C45</entry><entry morerows="1">106.(4)</entry></row><row><entry morerows="1">C6‑N3‑N2</entry><entry morerows="1">104.8(3)</entry><entry morerows="1">N7‑C26‑C24</entry><entry morerows="1">113.4(4)</entry></row><row><entry morerows="1">C7‑O2‑C8</entry><entry morerows="1">115.7(4)</entry><entry morerows="1">N7‑C26‑C27</entry><entry morerows="1">121.0(4)</entry></row><row><entry morerows="1">C17‑O7‑C18</entry><entry morerows="1">116.1(5)</entry><entry morerows="1">C27‑C26‑C24</entry><entry morerows="1">125.4(4)</entry></row><row><entry morerows="1">N16‑N17‑C63</entry><entry morerows="1">117.4(3)</entry><entry morerows="1">C39‑C43‑C44</entry><entry morerows="1">130.8(4)</entry></row><row><entry morerows="1">C62‑N17‑N16</entry><entry morerows="1">112.2(4)</entry><entry morerows="1">C39‑C43‑C42</entry><entry morerows="1">106.6(4)</entry></row><row><entry morerows="1">C62‑N17‑C63</entry><entry morerows="1">129.4(4)</entry><entry morerows="1">C42‑C43‑C44</entry><entry morerows="1">122.6(4)</entry></row><row><entry morerows="1">N11‑N12‑Cu2</entry><entry morerows="1">112.6(3)</entry><entry morerows="1">O10‑C25‑N8</entry><entry morerows="1">126.6(5)</entry></row><row><entry morerows="1">C39‑N12‑Cu2</entry><entry morerows="1">142.2(3)</entry><entry morerows="1">O10‑C25‑C24</entry><entry morerows="1">128.6(4)</entry></row><row><entry morerows="1">C39‑N12‑N11</entry><entry morerows="1">105.0(4)</entry><entry morerows="1">N8‑C25‑C24</entry><entry morerows="1">104.8(4)</entry></row><row><entry morerows="1">C63‑N18‑Cu1</entry><entry morerows="1">114.4(3)</entry><entry morerows="1">N9‑C29‑N8</entry><entry morerows="1">114.0(4)</entry></row><row><entry morerows="1">C63‑N18‑C67</entry><entry morerows="1">117.2(4)</entry><entry morerows="1">N9‑C29‑C30</entry><entry morerows="1">123.6(5)</entry></row><row><entry morerows="1">C67‑N18‑Cu1</entry><entry morerows="1">127.1(3)</entry><entry morerows="1">C30‑C29‑N8</entry><entry morerows="1">122.4(5)</entry></row><row><entry morerows="1">C5‑N1‑Cu1</entry><entry morerows="1">113.9(3)</entry><entry morerows="1">C65‑C64‑C63</entry><entry morerows="1">116.3(5)</entry></row><row><entry morerows="1">C1‑N1‑Cu1</entry><entry morerows="1">128.1(3)</entry><entry morerows="1">O4‑C12‑O5</entry><entry morerows="1">124.6(5)</entry></row><row><entry morerows="1">C1‑N1‑C5</entry><entry morerows="1">117.5(4)</entry><entry morerows="1">O4‑C12‑C11</entry><entry morerows="1">125.8(4)</entry></row><row><entry morerows="1">N3‑N2‑C9</entry><entry morerows="1">111.8(4)</entry><entry morerows="1">O5‑C12‑C11</entry><entry morerows="1">109.6(4)</entry></row><row><entry morerows="1">C5‑N2‑N3</entry><entry morerows="1">118.0(4)</entry><entry morerows="1">O7‑C17‑C16</entry><entry morerows="1">112.7(4)</entry></row><row><entry morerows="1">C5‑N2‑C9</entry><entry morerows="1">130.2(4)</entry><entry morerows="1">O6‑C17‑O7</entry><entry morerows="1">124.7(5)</entry></row><row><entry morerows="1">C40‑O12‑C41</entry><entry morerows="1">116.9(4)</entry><entry morerows="1">O6‑C17‑C16</entry><entry morerows="1">122.5(4)</entry></row><row><entry morerows="1">N17‑N16‑Cu1</entry><entry morerows="1">112.8(3)</entry><entry morerows="1">N14‑C58‑C62</entry><entry morerows="1">112.5(4)</entry></row><row><entry morerows="1">C59‑N16‑Cu1</entry><entry morerows="1">138.1(3)</entry><entry morerows="1">N14‑C58‑C59</entry><entry morerows="1">114.1(4)</entry></row><row><entry morerows="1">C59‑N16‑N17</entry><entry morerows="1">108.9(4)</entry><entry morerows="1">N14‑C58‑C44</entry><entry morerows="1">101.1(4)</entry></row><row><entry morerows="1">N8‑N7‑Cu2</entry><entry morerows="1">112.2(3)</entry><entry morerows="1">C62‑C58‑C44</entry><entry morerows="1">116.7(4)</entry></row><row><entry morerows="1">C26‑N7‑Cu2</entry><entry morerows="1">138.9(3)</entry><entry morerows="1">C59‑C58‑C62</entry><entry morerows="1">99.6(4)</entry></row><row><entry morerows="1">C26‑N7‑N8</entry><entry morerows="1">108.8(4)</entry><entry morerows="1">C59‑C58‑C44</entry><entry morerows="1">113.5(4)</entry></row><row><entry morerows="1">C45‑O15‑C46</entry><entry morerows="1">116.5(5)</entry><entry morerows="1">C57‑N15‑C53</entry><entry morerows="1">117.2(6)</entry></row><row><entry morerows="1">C38‑N10‑Cu2</entry><entry morerows="1">114.0(3)</entry><entry morerows="1">O15‑C45‑C44</entry><entry morerows="1">109.9(4)</entry></row><row><entry morerows="1">C38‑N10‑C34</entry><entry morerows="1">116.8(5)</entry><entry morerows="1">O14‑C45‑O15</entry><entry morerows="1">125.0(5)</entry></row><row><entry morerows="1">C34‑N10‑Cu2</entry><entry morerows="1">128.3(4)</entry><entry morerows="1">O14‑C45‑C44</entry><entry morerows="1">125.1(4)</entry></row><row><entry morerows="1">C12‑O5‑C13</entry><entry morerows="1">117.7(4)</entry><entry morerows="1">N13‑C50‑C44</entry><entry morerows="1">114.7(5)</entry></row><row><entry morerows="1">N7‑N8‑C29</entry><entry morerows="1">117.6(4)</entry><entry morerows="1">N13‑C50‑C51</entry><entry morerows="1">123.8(5)</entry></row><row><entry morerows="1">C25‑N8‑N7</entry><entry morerows="1">112.6(4)</entry><entry morerows="1">C51‑C50‑C44</entry><entry morerows="1">120.3(5)</entry></row><row><entry morerows="1">C25‑N8‑C29</entry><entry morerows="1">128.9(4)</entry><entry morerows="1">O13‑C42‑N11</entry><entry morerows="1">123.8(4)</entry></row><row><entry morerows="1">C27‑O9‑C28</entry><entry morerows="1">115.9(4)</entry><entry morerows="1">O13‑C42‑C43</entry><entry morerows="1">132.7(5)</entry></row><row><entry morerows="1">C29‑N9‑Cu2</entry><entry morerows="1">115.6(3)</entry><entry morerows="1">N11‑C42‑C43</entry><entry morerows="1">103.4(4)</entry></row><row><entry morerows="1">C29‑N9‑C33</entry><entry morerows="1">116.6(5)</entry><entry morerows="1">N10‑C38‑N11</entry><entry morerows="1">114.6(4)</entry></row><row><entry morerows="1">C33‑N9‑Cu2</entry><entry morerows="1">127.1(4)</entry><entry morerows="1">N10‑C38‑C37</entry><entry morerows="1">123.0(5)</entry></row><row><entry morerows="1">N12‑N11‑C42</entry><entry morerows="1">112.6(4)</entry><entry morerows="1">C37‑C38‑N11</entry><entry morerows="1">122.4(5)</entry></row></tbody></tgroup></table></tables><tables num="0004" id="ctbl0004"><table><tgroup cols="4"><colspec colname="c001" colwidth="21%" /><colspec colname="c002" colwidth="23%" /><colspec colname="c003" colwidth="31%" /><colspec colname="c004" colwidth="25%" /><tbody><row><entry morerows="1">N12‑N11‑C38</entry><entry morerows="1">117.9(4)</entry><entry morerows="1">C66‑C65‑C64</entry><entry morerows="1">121.3(5)</entry></row><row><entry morerows="1">C38‑N11‑C42</entry><entry morerows="1">129.4(4)</entry><entry morerows="1">N18‑C67‑Cl6</entry><entry morerows="1">115.7(4)</entry></row><row><entry morerows="1">C60‑O20‑C61</entry><entry morerows="1">115.3(6)</entry><entry morerows="1">N18‑C67‑C66</entry><entry morerows="1">124.0(5)</entry></row><row><entry morerows="1">C16‑N4‑N5</entry><entry morerows="1">109.1(4)</entry><entry morerows="1">C66‑C67‑Cl6</entry><entry morerows="1">120.3(4)</entry></row><row><entry morerows="1">O3‑C9‑N2</entry><entry morerows="1">123.3(4)</entry><entry morerows="1">N10‑C34‑Cl4</entry><entry morerows="1">115.1(4)</entry></row><row><entry morerows="1">O3‑C9‑C10</entry><entry morerows="1">132.5(4)</entry><entry morerows="1">N10‑C34‑C35</entry><entry morerows="1">124.9(6)</entry></row><row><entry morerows="1">N2‑C9‑C10</entry><entry morerows="1">104.2(3)</entry><entry morerows="1">C35‑C34‑Cl4</entry><entry morerows="1">119.9(4)</entry></row><row><entry morerows="1">N18‑C63‑N17</entry><entry morerows="1">114.4(4)</entry><entry morerows="1">O15‑C46‑C47</entry><entry morerows="1">107.9(6)</entry></row><row><entry morerows="1">N18‑C63‑C64</entry><entry morerows="1">123.6(5)</entry><entry morerows="1">N1‑C1‑Cl1</entry><entry morerows="1">114.5(4)</entry></row><row><entry morerows="1">C64‑C63‑N17</entry><entry morerows="1">122.0(4)</entry><entry morerows="1">N1‑C1‑C2</entry><entry morerows="1">125.8(5)</entry></row><row><entry morerows="1">C9‑C10‑C11</entry><entry morerows="1">124.5(4)</entry><entry morerows="1">C2‑C1‑Cl1</entry><entry morerows="1">119.7(5)</entry></row><row><entry morerows="1">C6‑C10‑C9</entry><entry morerows="1">106.1(4)</entry><entry morerows="1">C31‑C32‑C33</entry><entry morerows="1">117.7(6)</entry></row><row><entry morerows="1">C6‑C10‑C11</entry><entry morerows="1">129.4(4)</entry><entry morerows="1">C31‑C30‑C29</entry><entry morerows="1">117.1(7)</entry></row><row><entry morerows="1">N4‑N5‑C24</entry><entry morerows="1">113.5(4)</entry><entry morerows="1">C3‑C4‑C5</entry><entry morerows="1">116.8(5)</entry></row><row><entry morerows="1">N4‑N5‑C19</entry><entry morerows="1">121.7(4)</entry><entry morerows="1">O20‑C60‑C59</entry><entry morerows="1">109.4(5)</entry></row><row><entry morerows="1">C19‑N5‑C24</entry><entry morerows="1">123.2(4)</entry><entry morerows="1">O19‑C60‑O20</entry><entry morerows="1">126.5(5)</entry></row><row><entry morerows="1">N3‑C6‑C10</entry><entry morerows="1">113.1(4)</entry><entry morerows="1">O19‑C60‑C59</entry><entry morerows="1">124.0(5)</entry></row><row><entry morerows="1">N3‑C6‑C7</entry><entry morerows="1">118.2(4)</entry><entry morerows="1">N5‑C19‑C20</entry><entry morerows="1">121.7(6)</entry></row><row><entry morerows="1">C10‑C6‑C7</entry><entry morerows="1">128.6(4)</entry><entry morerows="1">N6‑C19‑N5</entry><entry morerows="1">114.8(5)</entry></row><row><entry morerows="1">N12‑C39‑C40</entry><entry morerows="1">116.9(4)</entry><entry morerows="1">N6‑C19‑C20</entry><entry morerows="1">123.6(6)</entry></row><row><entry morerows="1">N12‑C39‑C43</entry><entry morerows="1">112.4(4)</entry><entry morerows="1">O16‑C51‑O17</entry><entry morerows="1">126.5(6)</entry></row><row><entry morerows="1">C43‑C39‑C40</entry><entry morerows="1">130.5(4)</entry><entry morerows="1">O16‑C51‑C50</entry><entry morerows="1">121.6(6)</entry></row><row><entry morerows="1">C51‑O17‑C52</entry><entry morerows="1">113.5(6)</entry><entry morerows="1">O17‑C51‑C50</entry><entry morerows="1">111.9(6)</entry></row><row><entry morerows="1">N4‑C16‑C11</entry><entry morerows="1">115.0(4)</entry><entry morerows="1">N9‑C33‑Cl3</entry><entry morerows="1">114.9(5)</entry></row><row><entry morerows="1">N4‑C16‑C17</entry><entry morerows="1">122.1(4)</entry><entry morerows="1">N9‑C33‑C32</entry><entry morerows="1">124.2(6)</entry></row><row><entry morerows="1">C17‑C16‑C11</entry><entry morerows="1">121.8(4)</entry><entry morerows="1">C32‑C33‑Cl3</entry><entry morerows="1">120.9(5)</entry></row><row><entry morerows="1">N13‑N14‑C58</entry><entry morerows="1">113.8(4)</entry><entry morerows="1">O5‑C13‑C14</entry><entry morerows="1">108.1(6)</entry></row><row><entry morerows="1">N13‑N14‑C53</entry><entry morerows="1">120.6(5)</entry><entry morerows="1">C34‑C35‑C36</entry><entry morerows="1">116.8(5)</entry></row><row><entry morerows="1">C53‑N14‑C58</entry><entry morerows="1">123.1(4)</entry><entry morerows="1">C1‑C2‑C3</entry><entry morerows="1">114.6(6)</entry></row><row><entry morerows="1">O18‑C62‑N17</entry><entry morerows="1">126.1(4)</entry><entry morerows="1">C4‑C3‑C2</entry><entry morerows="1">122.8(6)</entry></row><row><entry morerows="1">O18‑C62‑C58</entry><entry morerows="1">128.1(4)</entry><entry morerows="1">N15‑C53‑N14</entry><entry morerows="1">113.3(5)</entry></row><row><entry morerows="1">N17‑C62‑C58</entry><entry morerows="1">105.8(4)</entry><entry morerows="1">N15‑C53‑C54</entry><entry morerows="1">123.4(6)</entry></row><row><entry morerows="1">N16‑C59‑C58</entry><entry morerows="1">113.4(4)</entry><entry morerows="1">C54‑C53‑N14</entry><entry morerows="1">123.3(6)</entry></row><row><entry morerows="1">N16‑C59‑C60</entry><entry morerows="1">118.7(4)</entry><entry morerows="1">N15‑C57‑Cl5</entry><entry morerows="1">116.0(5)</entry></row><row><entry morerows="1">C60‑C59‑C58</entry><entry morerows="1">127.9(4)</entry><entry morerows="1">N15‑C57‑C56</entry><entry morerows="1">124.2(7)</entry></row><row><entry morerows="1">C23‑N6‑C19</entry><entry morerows="1">118.1(5)</entry><entry morerows="1">C56‑C57‑Cl5</entry><entry morerows="1">119.7(6)</entry></row><row><entry morerows="1">O11‑C40‑O12</entry><entry morerows="1">125.0(4)</entry><entry morerows="1">C65‑C66‑C67</entry><entry morerows="1">117.5(5)</entry></row><row><entry morerows="1">O11‑C40‑C39</entry><entry morerows="1">124.2(4)</entry><entry morerows="1">C37‑C36‑C35</entry><entry morerows="1">120.5(6)</entry></row><row><entry morerows="1">O12‑C40‑C39</entry><entry morerows="1">110.8(4)</entry><entry morerows="1">C36‑C37‑C38</entry><entry morerows="1">117.9(6)</entry></row><row><entry morerows="1">C10‑C11‑C16</entry><entry morerows="1">113.4(4)</entry><entry morerows="1">C32‑C31‑C30</entry><entry morerows="1">120.7(7)</entry></row><row><entry morerows="1">C10‑C11‑C24</entry><entry morerows="1">113.5(3)</entry><entry morerows="1">N6‑C23‑Cl2</entry><entry morerows="1">115.4(5)</entry></row><row><entry morerows="1">C10‑C11‑C12</entry><entry morerows="1">112.2(4)</entry><entry morerows="1">N6‑C23‑C22</entry><entry morerows="1">124.8(8)</entry></row><row><entry morerows="1">C16‑C11‑C24</entry><entry morerows="1">98.9(3)</entry><entry morerows="1">C22‑C23‑Cl2</entry><entry morerows="1">119.7(6)</entry></row><row><entry morerows="1">C16‑C11‑C12</entry><entry morerows="1">106.0(4)</entry><entry morerows="1">C53‑C54‑C55</entry><entry morerows="1">115.7(8)</entry></row><row><entry morerows="1">C12‑C11‑C24</entry><entry morerows="1">111.9(4)</entry><entry morerows="1">C55‑C56‑C57</entry><entry morerows="1">117.5(7)</entry></row><row><entry morerows="1">O2‑C7‑C6</entry><entry morerows="1">111.4(4)</entry><entry morerows="1">C46‑C47‑C48</entry><entry morerows="1">110.6(8)</entry></row><row><entry morerows="1">O1‑C7‑O2</entry><entry morerows="1">125.2(4)</entry><entry morerows="1">C19‑C20‑C21</entry><entry morerows="1">114.1(8)</entry></row><row><entry morerows="1">O1‑C7‑C6</entry><entry morerows="1">123.4(4)</entry><entry morerows="1">C56‑C55‑C54</entry><entry morerows="1">121.9(8)</entry></row><row><entry morerows="1">N5‑C24‑C11</entry><entry morerows="1">101.3(3)</entry><entry morerows="1">C22‑C21‑C20</entry><entry morerows="1">122.4(8)</entry></row><row><entry morerows="1">N5‑C24‑C26</entry><entry morerows="1">113.2(4)</entry><entry morerows="1">C23‑C22‑C21</entry><entry morerows="1">116.8(8)</entry></row><row><entry morerows="1">N5‑C24‑C25</entry><entry morerows="1">112.4(4)</entry><entry morerows="1">C13‑C14‑C15</entry><entry morerows="1">117.6(13)</entry></row><row><entry morerows="1">C26‑C24‑C11</entry><entry morerows="1">112.6(4)</entry><entry morerows="1">C49‑C48‑C47</entry><entry morerows="1">112.9(12)</entry></row><row><entry morerows="1">C26‑C24‑C25</entry><entry morerows="1">100.3(4)</entry><entry morerows="1"> </entry><entry morerows="1"> </entry></row></tbody></tgroup></table></tables>。 |
