发明名称 LITHIUM-ION BATTERY POSITIVE ELECTRODE MATERIAL AND PREPARATION METHOD THEREOF
摘要 The present disclosure provides a lithium-ion battery positive electrode material and a preparation method thereof. In the lithium-ion battery positive electrode material, a secondary particle comprises lithium-containing multi-element transition metal oxide primary particles and a second phase material, a second phase material forms a second phase material layer distributed on a surface of the primary particle and forms a diffusion layer together with the lithium-containing multi-element transition metal oxide by means of atoms mutual diffusion to make the second phase material layer combined with the primary particle during formation of the secondary particle from the primary particles, thereby effectively suppressing chalking of the secondary particle along boundary among the primary particles, and effectively controlling size of the primary particles and the secondary particles, and improving specific capacity, cycling performance and safety performance of a lithium-ion battery to which the lithium-ion battery positive electrode material is applied.
申请公布号 US2015079471(A1) 申请公布日期 2015.03.19
申请号 US201414460229 申请日期 2014.08.14
申请人 Ningde Amperex Technology Limited ;Dongguan Amperex Technology Limited 发明人 FANG Xiangpeng;CHONG Jin;KUANG Quan;LIU Na
分类号 H01M4/36;H01M4/04;H01M10/0525;C01G53/00;H01M4/525;H01M4/505 主分类号 H01M4/36
代理机构 代理人
主权项 1. A lithium-ion battery positive electrode material, a secondary particle (SP) of the lithium-ion battery positive electrode material comprising lithium-containing multi-element transition metal oxide primary particles (PP) and a second phase material, a formula of the lithium-containing multi-element transition metal oxide being Li1+εNixCoyMnzM1-x-y-zO2-γAγ, in which −0.1<ε<0.1, 0<x, y, z<1, 1-x-y-z≧0, 0≦γ<0.3, M is a doping cation, A is a doping anion, M is selected from at least one of Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Al, Ga, In, Ge, Sn, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, A is selected from at least one of N, F, P, S, Cl and Se, the second phase material being selected from at least one of oxides, phosphates, sulfates, silicates of aluminum (Al), boron (B), magnesium (Mg), titanium (Ti), silicon (Si), vanadium (V), scandium (Sc), chromium (Cr), strontium (Sr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Nf) and wolfram (W), the second phase material forming a second phase material layer (ML) distributed on a surface of the lithium-containing multi-element transition metal oxide primary particle (PP) and forming a diffusion layer (DL) together with the lithium-containing multi-element transition metal oxide by means of atoms mutual diffusion to combine the second phase material layer (ML) with the lithium-containing multi-element transition metal oxide primary particle (PP) during formation of the secondary particle (SP) from the lithium-containing multi-element transition metal oxide primary particles (PP).
地址 Ningde CN