主权项 |
1. A lithium-ion battery positive electrode material, a secondary particle (SP) of the lithium-ion battery positive electrode material comprising lithium-containing multi-element transition metal oxide primary particles (PP) and a second phase material,
a formula of the lithium-containing multi-element transition metal oxide being Li1+εNixCoyMnzM1-x-y-zO2-γAγ, in which −0.1<ε<0.1, 0<x, y, z<1, 1-x-y-z≧0, 0≦γ<0.3, M is a doping cation, A is a doping anion, M is selected from at least one of Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Al, Ga, In, Ge, Sn, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, A is selected from at least one of N, F, P, S, Cl and Se, the second phase material being selected from at least one of oxides, phosphates, sulfates, silicates of aluminum (Al), boron (B), magnesium (Mg), titanium (Ti), silicon (Si), vanadium (V), scandium (Sc), chromium (Cr), strontium (Sr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Nf) and wolfram (W), the second phase material forming a second phase material layer (ML) distributed on a surface of the lithium-containing multi-element transition metal oxide primary particle (PP) and forming a diffusion layer (DL) together with the lithium-containing multi-element transition metal oxide by means of atoms mutual diffusion to combine the second phase material layer (ML) with the lithium-containing multi-element transition metal oxide primary particle (PP) during formation of the secondary particle (SP) from the lithium-containing multi-element transition metal oxide primary particles (PP). |