System and Method for Introducing an Additive into a Coking Process to Improve Quality and Yields of Coker Products

摘要

Heavy gas oil components, coking process recycle, and heavier hydrocarbons in the delayed coking process are cracked in the coking vessel by injecting a catalytic additive into the vapors above the gas/liquid-solid interface in the coke drum during the coking cycle. The additive comprises cracking catalyst(s) and quenching agent(s), alone or in combination with seeding agent(s), excess reactant(s), carrier fluid(s), or any combination thereof to modify reaction kinetics to preferentially crack these components. The quenching effect of the additive can be effectively used to condense the highest boiling point compounds of the traditional recycle onto the catalyst(s), thereby focusing the catalyst exposure to these target reactants. Exemplary embodiments of the present invention can also provide methods to (1) reduce coke production, (2) reduce fuel gas production, and (3) increase liquids production.

主权项

1. A process comprising introducing an additive comprising catalyst(s) into a coking vessel during a coking cycle of a delayed coking process such that said additive reduces the energy of activation for initiation of a catalytic reaction of a high boiling point material in said coking vessel.