摘要 |
本发明系关于一种两部分黏合组合物,其包括部分A及部分B。部分A包括有机硼烷-硷错合物及反应性稀释剂。反应性稀释剂包括:异三聚氰酸三烯丙酯;三聚氰酸三烯丙酯;具有式R 1 C(=O)N(R 2 )CH2CH=CH2之N-烯丙醯胺,其中R 1 及R 2 独立地表示具有1至7个碳原子之烷基,视情况由氧间杂至多3次,且视情况经羟基取代至多2次,或R 1 与R 2 结合在一起表示-(CH2)3-、-(CH2)4-或-(CH2)5-;及/或具有式R 3 [OCH2CH=CH2]n之烯丙醚,其中R 3 表示具有1至24个碳原子之n价烃基,视情况由氧间杂至多8次,且视情况经羟基取代至多6次,且n表示1、2、3、4、5或6。部分B包括可自由基聚合单体及至少一种能够解错合该有机硼烷-硷错合物之化合物。本发明亦揭示一种组合部分A与部分B之方法。; triallyl cyanurate; N-allylamide having the formula R 1 C(=O)N(R 2 )CH2CH=CH2, wherein R 1 and R 2 independently represent alkyl groups having from 1 to 7 carbon atoms, optionally interrupted up to 3 times by oxygen, and optionally substituted up to 2 times with hydroxyl groups, or taken together R 1 and R 2 represent-(CH2)3-, -(CH2)4-, or -(CH2)5-; and/or allyl ether having the formula R 3 [OCH2CH=CH2]nwherein R 3 represents an n-valent hydrocarbonaceous group having from 1 to 24 carbon atoms, optionally interrupted up to 8 times by oxygen, and optionally substituted up to 6 times with hydroxyl groups, and n represents 1, 2, 3, 4, 5, or 6. Part B includes free-radically polymerizable monomer and at least one compound capable of decomplexing the organoborane-base complex. A method combining Parts A and B is also disclosed. |