发明名称 Organic compound and solar cell using the same
摘要 Embodiments of the present invention provide an organic semiconductor excellent in the photoelectric conversion efficiency and also a solar cell using the same. This organic semiconductor has a polymer structure comprising a repeating unit represented by the following formula (I): -[A-D]- (I). In the formula, A is a structure represented by; and D is a structure having a benzodithiophene skeleton or the like. In the above, R1 is independently H, a substituted or unsubstituted straight-chain or branched-chain alkyl group, or a substituted or unsubstituted straight-chain or branched-chain alkoxy group. The solar cell according to an embodiment of the present invention comprises an active layer containing the organic semiconductor.
申请公布号 US8969718(B2) 申请公布日期 2015.03.03
申请号 US201313752475 申请日期 2013.01.29
申请人 Kabushiki Kaisha Toshiba 发明人 Iwanaga Hiroki;Ono Akihiko;Aiga Fumihiko
分类号 H01L31/00;H01L51/00;H01G9/20;C08G61/12;H01L51/42 主分类号 H01L31/00
代理机构 Amin, Turocy & Watson, LLP 代理人 Amin, Turocy & Watson, LLP
主权项 1. An organic compound which has a polymer structure comprising a repeating unit represented by the following formula (I): -[A-D]-  (I) wherein A is a structure represented by D is a structure selected from the group consisting of: structures represented by wherein the group from which D is selected further consists of structures comprising a skeleton from the group consisting of thiophene, selenophene, oligothiophene, oligoselenophene, alkoxybenzene, tolan, thienothiophene, carbazole, fluorene, 3,4-ethylenedioxythiophene, cyclopentadithiophene, dithienothiophene, heptadecanylcarbazole, phosphafluorene, thiazolothiazole, pyridine, phenylthiophene, phenanthroline, phenanthrene, thiadiazole, crown ether, arylamine, diketopyrrolopyrrole, thiophene-benzene-thiophene unit, and derivatives thereof; R1 is independently H, a substituted or unsubstituted straight-chain or branched-chain alkyl group, or a substituted or unsubstituted straight-chain or branched-chain alkoxy group, provided that plural R1s may be the same or different and at least one of R1 is a perfluoroalkyl group; R2 is independently a substituted or unsubstituted straight-chain or branched-chain alkyl group, a substituted or unsubstituted straight-chain or branched-chain alkoxy group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted thienyl group, or a substituted or unsubstituted selenophene group, provided that plural R2s may be the same or different; m is independently an integer of 0 to 4, provided that plural ms may be the same or different; X is independently an element selected from the group consisting of O, S, Se, Te and N, provided that plural Xs may be the same or different; Z is an element selected from the group consisting of H, F, Cl, Br and I; W is a substituted or unsubstituted straight-chain or branched-chain alkyl group, a substituted or unsubstituted straight-chain or branched-chain alkoxy group, or a ketone or ester group substituted with a substituted or unsubstituted straight-chain or branched-chain alkyl group; V is a group selected from the group consisting of —CR32—, —SiR32— and —NR3— in which R3 is a substituted or unsubstituted straight-chain or branched-chain alkyl group, provided that, if there are two or more R3s, they may be the same or different; and a repeating unit represented by the following formula (II): -[A′-D]-  (11); wherein A′ is a structure represented by D is a structure selected from the same group as that in the formula (1); R1′is independently H, a substitute or unsubstituted straight-chain or branched-chain alkyl group, or a substituted or unsubstituted straight-chain or branched alkoxy group, provided that plural R1's may be the same or different; and m′ is independently an integer of 0 to 5, provided that plural m's may be the same or different, wherein A is the formula (1) includes two or more different repeating units.
地址 Tokyo JP