Aliphatic polyester resin and its production method

摘要

A method of producing an aliphatic polyester resin by continuously esterifying and melt polycondensing an aliphatic dicarboxylic acid and an aliphatic diol; and at least one aliphatic hydroxycarboxylic acid; and at least one of an aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids, wherein the total amount of the at least one aliphatic hydroxycarboxylic acid and the at least one of aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids is from 0.0010 to 0.50 mol % of the total amount of the aliphatic polyester resin; and the total amount of the at least one aliphatic hydroxycarboxylic acid is from 1.0 to 7.0 in terms of a molar ratio to the total amount of the at least one of aliphatic unsaturated dicarboxylic acid and cis- and trans-isomers of aliphatic unsaturated tricarboxylic acids.

主权项

1. A method of producing an aliphatic polyester resin, comprising
continuously reacting the units represented by formula (1); formula (2); at least one of formula (3) and formula (4); and at least one of formula (5), formula (6), and formula (7) in plural continuous reaction tanks, wherein said continuously reacting comprises esterifying and melt polycondensing, wherein said aliphatic dicarboxylic acid represented by formula (1) and said aliphatic diol represented by formula (2) are comprised as main components, a reduced viscosity at 30° C. of the aliphatic polyester resin is from 1.6 to 3 dL/g, and wherein:
(CO)—R1—(CO)  (1)wherein R1 represents an aliphatic saturated hydrocarbon group having from 0 to 40 carbon atoms,
O—R2—O  (2)wherein R2 represents an aliphatic hydrocarbon group having from 2 to 10 carbon atoms,wherein R3 represents an aliphatic hydrocarbon group having from 1 to 20 carbon atoms,wherein R4 represents an aliphatic hydrocarbon group having from 1 to 20 carbon atoms,
(CO)—R5—(CO)  (5)wherein R5 represents an aliphatic hydrocarbon group having from 2 to 20 carbon atoms, having at least one double bond, wherein the formula (6) and the formula (7) are geometric isomers regarding double bond, the formula (6) represents a trans form and the formula (7) represents a cis form, r and s each independently are an integer of from 0 to 17, R8 represents hydrogen or an aliphatic hydrocarbon group having from 1 to 17 carbon atoms, wherein the total amount of units represented by the formula (3), the formula (4), the formula (5), the formula (6) and the formula (7) is from 0.0010 to 0.50 mol % to 100 mol % of the total amount of all units in the aliphatic polyester resin; and wherein the total of the units represented by the formula (3) and the formula (4) is from 1.0 to 7.0 in terms of molar ratio to the total of the units represented by the formula (5), the formula (6) and the formula (7).