| 摘要 |
<p>A Ni-Fe-Cr-Mo alloy containing a small amount of Cu and correlated percentages of Nb, Ti and AI to develop a unique microstructure to produce 145 ksi minimum yield strength. The unique microstructure is obtained by special annealing and age hardening conditions, by virtue of which the alloy has an attractive combination of yield strength, impact strength, ductility, corrosion resistance, thermal stability and formability, and is especially suited for corrosive oil well applications that contain gaseous mixtures of carbon dioxide and hydrogen sulfide. The alloy comprises in weight percent the following: 0-15% Fe, 18-24% Cr, 3-9% Mo, 0.05 3.0% Cu, 3.6-6.5% Nb, 0.5-2.2% Ti, 0.05-1.0% AI, 0.005-0.040% C, balance Ni plus incidental impurities and a ratio of M Nb/(Al+ Ti) in the range of 2.5-7.5. To facilitate formability, the composition range of the alloy is balanced to be Laves phase free. According to the disclosed method of manufacture, the above alloy is provided and hot worked to a desired shape such as a bar or tube for corrosive oil and gas deep wells. The shaped alloy is heat treated by solution annealing, quenching or air cooling, followed by one or two aging steps to precipitate.y' and y" phases.</p> |
