REACTIVE DYES, THEIR PREPARATION AND THEIR USE

摘要

Reactive dyes of formula (1), wherein Me is chromium, cobalt or iron, R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, E is a bivalent radical of formula (1a), (1b) or (1c) wherein X denotes chlorine or fluorine, T is a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), or (2f), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a—CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a—CH(Hal)-CH2-Hal or—C(Hal)=CH2 group, q is the number 0 or 1, G is a bivalent radical of formula (1d) or (1e) wherein (R2)s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C1-C4alkyl, C2-C4alkanoylamino, C1-C4alkylsulfonyl, carbamoyl, sulfamoyl, sulfo and -E-T, wherein E and T are as defined above, s is the number 0, 1, 2 or 3, A denotes a bivalent radical of formula (3a), (3b) or (3c), wherein R1, R2, X, T, q and s are as defined above, R4 and R7 denote hydrogen, C1-C4alkyl,—COOH or—COO—C1-C4alkyl, R5 and R6 represent, each independently of the other, identical or different substituents from the group hydroxyl, halogen, nitro, unsubstituted or halo-substituted C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, C1-C4alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, and t and u are each independently of the other the number 0, 1, 2 or 3, are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.