<p>This invention relates to an improved one-pot synthetic process for the preparation of glycidol from the reaction of glycerol and dimethyl carbonate. More specifically, the invention relates to a one-pot synthetic process for the preparation of glycidol comprising the reaction of glycerol and dimethyl carbonate in the presence of an ionic liquid catalyst having the formula: [Cat+][X] wherein: [Cat] represents one or more cationic species, and [X] represents one or more anionic species; wherein the reaction is conducted at a temperature of from 100°C to 160°C and wherein the molar ratio of glycerol to dimethylcarbonate is from 1:4 to 1:10.</p>
申请公布号
WO2015019108(A1)
申请公布日期
2015.02.12
申请号
WO2014GB52435
申请日期
2014.08.08
申请人
THE QUEEN'S UNIVERSITY OF BELFAST;COLEMAN, FERGAL;HOLBREY, JOHN;SEDDON, KENNETH;ATKINS, MARTIN;DELAVOUX, YOAN;TOLAND, JENI;YAN, TING