CATALYST SYSTEMS FOR USE IN CONTINUOUS FLOW REACTORS AND METHODS OF MANUFACTURE AND USE THEREOF

摘要

The present application provides a composite material and system for use in a heterogeneous flow reactor, comprising: a catalytic polymeric framework comprising catalyst-containing monomeric units derived from a diphosphine ligand, each separated by at least one non-catalyst containing monomeric unit; and a support material, wherein the catalytic polymeric framework is covalently or non-covalently immobilized on or in the support material. Each catalyst-containing monomeric subunit comprises a transitional metal bound to the diphosphine ligand. Also methods of manufacture and use of the catalyst system and composite material are provided.