PERFECTIONNEMENTS AUX PILES ALCALINES A ELECTROLYTE GELIFIE

摘要

1364376 Oxygen-depolarized cells SOC DES ACCUMULATEURS FIXES ET DE TRACTION 28 June 1972 [30 June 1971] 30361/72 Heading H1B A zinc-air cell has an expansion space 20 to allow for expansion of the negative active mass (NAM) 2 during discharge of the cell and to prevent oxygen in this space attacking the NAM has the latter cowered with a portion 21 of the gelled alkaline electrolyte 3. The cell may have a plastics case 1 and apertured lid 7, a NAM 2 consisting of amalgamated zinc particles suspended in aqueous potassium hydroxide gelled with native or modified starch at a concentration of 180-270 grammes/litre-1, an electrolyte 3 of aqueous potassium hydroxide gelled with a slightly lesser concentration of native or modified starch in the range 150-240 grammes/litre-1, and a positive electrode 4 made from a plastics-bound (using a copolymer of ethylene and vinyl acetate) mixture of soot, carbon, and manganese dioxide. The electrolyte is protected against carbonation during storage by a thin pitch layer 19 which fissures when NAM 2 expansion and consequent electrolyte 3 displacement occur during discharge. An apertured steel tube 6 runs down the centre of the cell and acts both as air/oxygen inlet and as positive current collector. It is connected to a brass or steel cap 9 and a brass terminal 10. The negative current collector is a copper wire 11 with a brass terminal 12. Precautions taken to avoid oxygen leakage to the NAM along the base of the cell consist of a cardboard disc 15 and pitch 16 in the steel tube 6 and surrounding pitch in the positive electrode. The expansion space is also closed by a cardboard disc 13 and a pitch layer 14.