发明名称 Branched poly(trimethylene ether) polyols
摘要 Disclosed is branched poly(trimethylene ether) polyols prepared from the acid catalyzed polycondensation reaction of 1,3-propanediol, and at least one triol comonomer selected from 1,1,1-tris(hydroxymethyl)ethane and 1,1,1-tris(hydroxymethyl)propane. Also disclosed is a branched poly(trimethylene ether) polyol with an equivalent hydroxyl functionality of about 2.1 to about 3.2 and a Mn of about 200 to about 6000. The polyols are useful in the preparation of polyurethane rigid and flexible foams.
申请公布号 US8946485(B2) 申请公布日期 2015.02.03
申请号 US201113220030 申请日期 2011.08.29
申请人 E I du Pont de Nemours and Company 发明人 Fenyvesi Gyorgyi;Poladi Raja Hari;Sunkara Hari Babu
分类号 C07C43/178;C07C43/15 主分类号 C07C43/178
代理机构 代理人
主权项 1. A branched amorphous poly(trimethylene ether) polyol comprising repeating units of Formula I, Formula II, and Formula IIIwherein R is methyl and Q is selected from Formula (IIIa) and (IIIb):wherein m is 1-20 and n is 1 to 3, and further comprising end groups of Formula IV, V, and VI:and wherein the branched poly(trimethylene ether) polyol comprises the repeating units of Formula II and Formula III, together, from about 2.8 mole % to about 10 mole %, and wherein the branched poly(trimethylene ether) polyol is amorphous.
地址 Wilmington DE US