Colquiriite-type crystal, scintillator for neutron detection and neutron detector

摘要

[Problems to be Solved] A colquiriite-type crystal preferred for a scintillator for neutron detection, which has high sensitivity to neutron and which is reduced in background noise attributed to γ rays; a scintillator for neutron detection which comprises this crystal; and a neutron detector are provided.;[Means to Solve the Problems] A colquiriite-type crystal represented by the chemical formula LiM1M2X6, such as LiCaAlF6, containing Na and Ce, for example, the colquiriite-type crystal containing at least one alkali metal element selected from the group consisting of Na, K, Rb and Cs, and a lanthanoid element selected from the group consisting of Ce, Pr and Nd, and having an isotopic ratio of 6Li of 20 mol % or more, preferably 50 mol % or more; a scintillator for neutron detection comprising the colquiriite-type crystal; and a neutron detector.

主权项

1. A colquiriite-type crystal represented by the chemical formula LiM1M2X6, wherein M1 represents at least one alkaline earth metal element selected from the group consisting of Mg, Ca, Sr and Ba, M2 represents at least one metal element selected from the group consisting of Al, Ga and Sc, and X represents at least one halogen element selected from the group consisting of F, Cl, Br and I,
wherein the colquiriite-type crystal contains at least one alkali metal element selected from the group consisting of Na, K, Rb and Cs, and at least one lanthanoid element selected from the group consisting of Ce, Pr and Nd, and an isotopic ratio of 6Li is 20% or more; and wherein contents of the alkali metal element and the lanthanoid element are 0.001 to 10 mol % and 0.01 to 0.5 mol %, respectively, with respect to the colquiriite-type crystal.