发明名称 Shrinkage-reducing agent for hydraulic material
摘要 Provided is a shrinkage-reducing agent for a hydraulic material, which does not require a combination with any other admixture, is inexpensive, and is capable of suppressing a reduction in strength of a hardened concrete material, suppressing generation of a crack in a hardened concrete material by virtue of its excellent shrinkage-reducing ability, and imparting excellent freeze-thaw resistance. The shrinkage-reducing agent for a hydraulic material includes at least one kind of polyoxyalkylene compound (A) as an essential component, in which a concrete or a mortar produced by using the shrinkage-reducing agent for a hydraulic material has a spacing factor of 350 μm or less.
申请公布号 US8933151(B2) 申请公布日期 2015.01.13
申请号 US201113520986 申请日期 2011.01.07
申请人 Nippon Shokubai Co., Ltd. 发明人 Masanaga Mari;Fukuhara Koji
分类号 C07C43/10;C08L97/00 主分类号 C07C43/10
代理机构 Sughrue Mion, PLLC 代理人 Sughrue Mion, PLLC
主权项 1. A shrinkage-reducing agent for a hydraulic material, comprising at least one kind of polyoxyalkylene compound (A), which is a compound selected from the group consisting of (i) polyalkyleneglycols, (ii) oxyethylene adducts of lower alcohols and higher alcohols each having 8 or more carbon atoms, and (iii) adducts of two or more kinds of oxyalkylenes essentially including an oxyethylene of lower alcohols and higher alcohols each having 8 or more carbon atoms, as an essential component, wherein a concrete or a mortar produced by using the shrinkage-reducing agent for a hydraulic material has a spacing factor of 350 μm or less, further comprising a water-reducing admixture (B); and an air entraining admixture (C) and an antifoaming agent (D), wherein a content ratio of the air entraining admixture (C) to the antifoaming agent (D), the air entraining admixture (C)/the antifoaming agent (D), is 99/1 to 5/95 as a weight ratio in terms of solid content, wherein the water-reducing admixture (B) is at least one kind of compound selected from the group consisting of a lignin sulfonate, a naphthalene sulfonic acid-formalin condensate, and a polymer having a polyoxyalkylene group and an anionic group, wherein the air entraining admixture (C) is at least one kind of compound selected from the group consisting of resin soaps, saturated or unsaturated fatty acids, sodium hydroxystearate, lauryl sulfate, alkylbenzenesulfonates, linear alkylbenzenesulfonates, alkanesulfonates, polyoxyethylene alkyl (phenyl) ethers, polyoxyethylene alkyl (phenyl) ether sulfuric acid esters or salts thereof, polyoxyethylene alkyl (phenyl) ether phosphoric acid esters or salts thereof, proteinic materials, alkenylsulfosuccinates, and α-olefin sulfonates, wherein the antifoaming agent (D) is at least one kind of compound selected from the group consisting of mineral oil-based antifoaming agents, fat and oil-based antifoaming agents, fatty acid-based antifoaming agents, fatty acid ester-based antifoaming agents, oxyalkylene-based antifoaming agents, alcohol-based antifoaming agents, amide-based antifoaming agents, phosphoric acid ester-based antifoaming agents, and metal soap-based antifoaming agents, and wherein the ratio of the total amount of the polyoxyalkylene compound (A) and the water-reducing admixture (B) to the total amount of the entraining admixture (C) and the antifoaming agent (D) is 99.99/0.01 to 98/2 as a weight ratio in terms of solid content.
地址 Osaka JP