发明名称 Manufacturing method of positive electrode active material and positive electrode active material
摘要 A positive electrode active material for nonaqueous electrolyte secondary batteries includes a coating layer containing at least nickel (Ni) and/or manganese (Mn) on the surface of a complex oxide particle containing lithium (Li) and cobalt (Co), wherein a binding energy value obtained by analysis of a surface state by an ESCA surface analysis on the surface of the coating layer is 642.0 eV or more and not more than 642.5 eV in an Mn2p3 peak, and a peak interval of Co—Mn is 137.6 eV or more and not more than 138.0 eV.
申请公布号 US8920973(B2) 申请公布日期 2014.12.30
申请号 US200912629489 申请日期 2009.12.02
申请人 Sony Corporation 发明人 Takei Yuki
分类号 H01M4/00;H01M4/13;H01M6/00;H01M10/00;H01M4/58;H01M2/16;C23C14/00;C23C14/32;H01M4/02;H01M4/29;H01M10/44;H01M4/50;H01M4/525;H01M4/36;H01M4/505 主分类号 H01M4/00
代理机构 K&L Gates LLP 代理人 K&L Gates LLP
主权项 1. A positive electrode active material for nonaqueous electrolyte secondary batteries comprising a coating layer containing at least one of nickel and manganese on a surface of a complex oxide particle containing lithium and cobalt, wherein: a binding energy value obtained by analysis of a surface state by an ESCA surface analysis on the surface of the coating layer is 642.0 eV or more and not more than 642.5 eV in an Mn2p3 peak, and a peak interval of Co—Mn is 137.6 eV or more and not more than 138.0 eV; and the positive electrode active material has an average composition represented by the following general formula (1) LipNi(1-q-r-s)MnqCorM1sO(2-y)  (1) wherein M1 represents at least one member selected among elements belonging to the Groups 2 to 15 but other than nickel, manganese and cobalt; and p, q, r, s and y represent values falling within the ranges of 0≦p≦1.5, 0≦q≦1.0, 0≦r≦1.0, 0≦s≦1.0 and −0.10≦y≦0.20, respectively; and wherein the complex oxide particle is subjected to a heat treatment after the coating layer is formed thereon, wherein the heat treatment is performed under an inert atmosphere.
地址 Tokyo JP