发明名称 Method for producing glycol from polyhydric alcohol
摘要 An object of the invention is to provide a production method that can produce glycol from polyhydric alcohol with high selectivity and in a satisfactory yield. The object is achieved by using a silver catalyst in a reaction for synthesizing hydroxyketone from polyhydric alcohol having adjacent hydroxyl groups, and a hydrogenation catalyst in a reaction for synthesizing glycol from hydroxyketone.
申请公布号 US8921616(B2) 申请公布日期 2014.12.30
申请号 US201213979373 申请日期 2012.01.12
申请人 Clariant Catalysts (Japan) K.K.;National University Corporation Chiba University 发明人 Kizaki Tetsuro;Iwatani Keizo;Chen Xin;Sato Satoshi
分类号 C07C27/04;C07C27/00;C07C29/145;B01J23/50;B01J23/89;C07C29/143;C07C45/52 主分类号 C07C27/04
代理机构 Jianq Chyun IP Office 代理人 Jianq Chyun IP Office
主权项 1. A method for producing glycol from polyhydric alcohol having adjacent hydroxyl groups, comprising a reaction for synthesizing hydroxyketone from polyhydric alcohol by using a silver catalyst and a reaction for synthesizing glycol from the hydroxyketone formed in the reaction described above by using a hydrogenation catalyst, wherein the reaction for synthesizing hydroxyketone and the reaction for synthesizing glycol continuously progress in one reaction system by using a catalyst containing both silver and copper and a gas-phase flow reaction apparatus, and pressure conditions in the reaction for synthesizing hydroxyketone and the reaction for synthesizing glycol are 1 MPa or less.
地址 Tokyo JP