| 发明名称 | Method for synthesising bis[3-(N,N-dialkylamino)propyl]ethers | ||
| 摘要 | The invention relates to an improved method for synthesizing bis[3-(N,N-dialkylamino)propyl]ethers from acrylonitrile, comprising the following reactions: first addition reaction of a water molecule and an acrylonitrile molecule to produce 3-hydroxypropionitrile (reaction 1),second addition reaction of a 3-hydroxypropionitrile molecule obtained by reaction 1 and an acrylonitrile molecule to produce bis(2-cyanoethyl)ether (reaction 2),hydrogenation reaction of the bis(2-cyanoethyl)ether to conduct a reduction of the nitrile functions to primary amine functions in order to produce bis(3-aminopropyl)ether (reaction 3),aminoalkylation reaction of the bis(3-aminopropyl)ether to produce bis[3-(N,N-dialkylamino)propyl]ether (reaction 4). | ||
| 申请公布号 | US8921602(B2) | 申请公布日期 | 2014.12.30 |
| 申请号 | US201214361307 | 申请日期 | 2012.10.18 |
| 申请人 | IFP Energies Nouvelles | 发明人 | Delfort Bruno;Le Pennec Dominique;Grandjean Julien |
| 分类号 | C07C213/02 | 主分类号 | C07C213/02 |
| 代理机构 | Antonelli, Terry, Stout & Kraus, LLP. | 代理人 | Antonelli, Terry, Stout & Kraus, LLP. |
| 主权项 | 1. A method for synthesizing bis[3-(N,N-dialkylamino)propyl]ethers from acrylonitrile, comprising the following reactions: first addition reaction of a water molecule and an acrylonitrile molecule to produce 3-hydroxypropionitrile (reaction 1), second addition reaction of a 3-hydroxypropionitrile molecule obtained by reaction 1 and an acrylonitrile molecule to produce bis(2-cyanoethyl)ether (reaction 2), hydrogenation reaction of the bis(2-cyanoethyl)ether to conduct a reduction of the nitrile functions to primary amine functions in order to produce bis(3-aminopropyl)ether (reaction 3), aminoalkylation reaction of the bis(3-aminopropyl)ether to produce bis[3-(N,N-dialkylamino)propyl]ether (reaction 4). | ||
| 地址 | Rueil-Malmaison Cedex FR | ||