发明名称 METHOD FOR PRODUCING POLYVALENT GLYCIDYL COMPOUND
摘要 <p>PROBLEM TO BE SOLVED: To provide a method capable of efficiently producing a polyvalent glycidyl compound in which a side reaction such as hydrolysis of a glycidyl ether group originally present in a compound, gelation caused by hydrolysis and the like are suppressed when oxidizing a 2-alkenyl group of a glycidyl ether compound having a 2-alkenyl group by using a hydrogen peroxide aqueous solution as an oxidant.SOLUTION: There is provided a method for producing a polyvalent glycidyl compound by controlling a pH of a reaction solution containing a glycidyl ether compound having one or more substituted or unsubstituted glycidyl ether groups and two or more substituted or unsubstituted 2-alkenyl groups in the molecule to 1.0 to 4.0 in the presence of a tungsten compound as a catalyst, two or more acids containing at least phosphoric acid and a quaternary ammonium salt using a hydrogen peroxide aqueous solution as an oxidant, adding a hydrogen peroxide aqueous solution to the reaction solution over 0.1 to 2 hours, and after the completion of addition of the hydrogen peroxide aqueous solution, terminating the reaction for 2 to 6 hours.</p>
申请公布号 JP2014240376(A) 申请公布日期 2014.12.25
申请号 JP20130245273 申请日期 2013.11.27
申请人 SHOWA DENKO KK 发明人 YAMASHITA CHIKA;ISHIBASHI YOSHITAKA
分类号 C07D303/30;C07D301/12;C08G59/02 主分类号 C07D303/30
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