Dithiocarbamic acid ester

摘要

Haloalkenyl dithiocarbamate esters (I) are new. Haloalkenyl dithiocarbamate esters of formula (I) are new: R = haloalkenyl; Z' = N(A)(B); A, B = H or optionally substituted alkyl, alkenyl, alkoxy, acyl, aroyl, aryl, heteroaryl, alkylsulfonyl, alkylsulfinyl, alkylphosphonyl, arylsulfinyl or arylphosphonyl, or A+B forms an optionally substituted heterocyclic group, provided that HN(A)(B) has a pKa of 12-20. Independent claims are also included for: (1) a process for preparing (I); (2) production of polymers by polymerizing monomers in the presence of (I); (3) a polymer produced as above; (4) a polymer with terminal Z-C(S)-S- groups and terminal R groups.