发明名称 |
Electrode material, a battery electrode, method of producing them, nonaqueous electrolyte battery and battery pack |
摘要 |
According to one embodiment, there is provided an electrode material. The electrode material includes an active material which includes a titanium oxide compound having a monoclinic titanium dioxide crystal structure. The electrode material further includes a compound which exists on the surface of the active material and has a trialkylsilyl group represented by the formula (I).;
wherein R1, R2 and R3, which may be the same or different, respectively represent an alkyl group having 1 to 10 carbon atoms. |
申请公布号 |
US8895188(B2) |
申请公布日期 |
2014.11.25 |
申请号 |
US201113071018 |
申请日期 |
2011.03.24 |
申请人 |
Kabushiki Kaisha Toshiba |
发明人 |
Hoshina Keigo;Zhang Wen;Harada Yasuhiro;Inagaki Hiroki;Takami Norio |
分类号 |
H01M10/0564;H01M4/04;H01M4/60;H01M10/0525;H01M4/58;H01M4/66;H01M10/0566 |
主分类号 |
H01M10/0564 |
代理机构 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. |
代理人 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. |
主权项 |
1. An electrode material comprising:
an active material comprising a titanium oxide compound having a monoclinic titanium dioxide crystal structure; and a compound which exists on a surface of the active material and has a trialkylsilyl group represented by the formula (I):wherein, R1, R2 and R3, which may be the same or different, respectively represent an alkyl group having 1 to 10 carbon atoms;
wherein the compound having the trialkylsilyl group is at least one selected from phosphoric acid compounds containing the trialkylsilyl group and boric acid compounds containing the trialkylsilyl group; and when a surface of the electrode material is measured by time-of-flight type secondary ion mass-analysis method, a peak intensity ratio (I1/I2) satisfies the equation (II):
3.30≦I1/I2 (II)wherein I1 is a peak intensity of Si(CH3)3+ and I2 is a peak intensity of Ti+. |
地址 |
Tokyo JP |