| 主权项 |
1. A fungicidal composition, comprising a combination of components A) and B), wherein component A) is a compound of formula (I) wherein R1 and R2 are each independently selected from hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl, (R10)carbonyl and (R10)oxycarbonyl; or R1 and R2 together with the nitrogen atom to which they are attached form a 5- or 6 membered cyclic group which may be saturated or unsaturated and may contain a further heteroatom selected from S or O; R3 represents hydrogen, halogen, cyano, nitro, mercapto, hydroxy, —C(═S)NH2, —SF5, C1-C6 alkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, C2-C6 haloalkynyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C3-C6 cycloalkyl, amino, C1-C2 alkylamino, di(C1-C6alkyl)amino, a 5-membered heterocycle containing 1-4 nitrogen atoms, piperidino, morpholino, thiomorpholino, formyl, hydroxycarbonyl, C2-C7 alkoxycarbonyl, C2-C7 haloalkoxycarbonyl, C4-C7 alkenyloxycarbonyl, C4-C7 haloalkenyloxycarbonyl, C2-C7 alkylcarbonyl, C2-C7 haloalkylcarbonyl, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylthio, C1-C6 haloalkylsulfinyl, C C6 haloalkylsulfonyl, C1-C6 hydroxyalkyl, phenyl or benzyl wherein the phenyl and benzyl are optionally substituted by one or more groups independently selected from the group consisting of halogen, cyano, hydroxy, mercapto, amino, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl; R4 represents hydrogen, halogen, cyano, amino, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C2-C4 alkenyl, C2-C4 alkynyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkylsulfonyl, methylamino or dimethylamino; R5 is hydrogen, C1-C12alkyl, C3-C12alkenyl, C3-C12alkynyl, C1-C12alkylsulfonyl, C2-C12alkenylsulfonyl, phenylsulfonyl or benzylsulfonyl, or is C1-C12alkyl, C2-C12alkenyl, C2-C12alkynyl, C1-C12alkylsulfonyl, C2-C12alkenylsulfonyl, phenylsulfonyl or benzylsulfonyl mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxy, mercapto, azido, formyl, C2-C7alkylcarbonyl, C2-C7haloalkylcarbonyl, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylthio, C1-C6alkylsulfinyl and C1-C6alkylsulfonyl; or R5 is formyl, C2-C12 alkylcarbonyl, C3-C12 alkenylcarbonyl, C3-C12 alkynylcarbonyl, C4-C12 cycloalkylcarbonyl, benzylcarbonyl, phenylcarbonyl, C2-C12 alkoxycarbonyl, C4-C12 alkenyloxycarbonyl, C4-C12 alkynyloxycarbonyl, C4-C12 cycloalkoxycarbonyl, benzyloxycarbonyl or phenoxycarbonyl, or is C2-C12 alkylcarbonyl, C3-C12 alkenylcarbonyl, C3-C12 alkynylcarbonyl, C4-C12 cycloalkylcarbonyl, benzylcarbonyl, phenylcarbonyl, C2-C12 alkoxycarbonyl, C4-C12 alkenyloxycarbonyl, C4-C12 alkynyloxycarbonyl, C4-C12 cycloalkoxycarbonyl, benzyloxycarbonyl or phenoxycarbonyl mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, C1-C6 alkyl, C1-C6 haloalkyl and C1-C6 alkoxy; or R5 is (R51)(R52)(R53)Si—, (R51)(R52)(R53)Si—(C1-C12alkyl)-, (R51)(R52)(R53)Si—(C3-C8cycloalkyl)-, (R54O)(R55O)(R56O)Si—, (R54O)(R55O)(R56O)Si—(C1-C12 alkyl)- or (R54O)(R55O)(R56O)Si—(C3-C8 cycloalkyl)-; or R5 is C1-C6alkyl-B—C1-C12alkyl-, C2-C6alkenyl-B—C1-C12alkyl-, C2-C6alkynyl-B—C1-C12alkyl-, C3-C8cycloalkyl-B—C1-C12alkyl-, benzyl-B—C1-C12alkyl-, phenyl-B—C1-C12alkyl-, C1-C6alkyl-B—C2-C12alkenyl-, C2-C6alkenyl-B—C2-C12alkenyl-, C2-C6alkynyl-B—C2-C12alkenyl-, C3-C8cycloalkyl-B—C2-C12alkenyl-, benzyl-B—C2-C12alkenyl-, phenyl-B—C2-C12alkenyl-, C1-C6alkyl-B—C2-C12alkynyl-, C2-C6alkenyl-B—C2-C12alkynyl-, C2-C6alkynyl-B—C2-C12alkynyl-, C3-C8cycloalkyl-B—C2-C12alkynyl-, benzyl-B—C2-C12alkynyl-, phenyl-B—C2-C12alkynyl-, C1-C6alkyl-B—C3-C8cycloalkyl-, C2-C6alkenyl-B—C3-C8cycloalkyl-, C2-C6alkynyl-B—C3-C8cycloalkyl-, C3-C8cycloalkyl-B—C3-C8cycloalkyl-, benzyl-B—C3-C12cycloalkyl- or phenyl-B—C3-C12cycloalkyl-, wherein the group B is selected from —C(═O)—, —C(═S)—, —C(═NOR59)—, —C(R60)═NO—, —ON═C(R60)—, —O—C(═O)—, —C(═O)—O—, —O—, —S—, —S(═O)—, —S(═O)2—, —S(═O)(═NR13)—, —S(═O)(R14)═N—, —N═S(═O)(R14)—, —N(R62)—C═O)—, —C═O)—N(R62)—, —N(R62)—SO2— or —SO2—N(R62)—; or R5 is C1-C6alkyl-B—C1-C12alkyl-, C2-C6alkenyl-B—C1-C12alkyl-, C2-C6alkynyl-B—C1-C12alkyl-, C3-C8cycloalkyl-B—C1-C12alkyl-, benzyl-B—C1-C12alkyl-, phenyl-B—C1-C12alkyl-, C1-C6alkyl-B—C2-C12alkenyl-, C2-C6alkenyl-B—C2-C12alkenyl-, C2-C6alkynyl-B—C2-C12alkenyl-, C3-C8cycloalkyl-B—C2-C12alkenyl-, benzyl-B—C2-C12alkenyl-, phenyl-B—C2-C12alkenyl-, C1-C6alkyl-B—C2-C12alkynyl-, C2-C6alkenyl-B—C2-C12alkynyl-, C2-C6alkynyl-B—C2-C12alkynyl-, C3-C8cycloalkyl-B—C2-C12alkynyl-, benzyl-B—C2-C12alkynyl-, phenyl-B—C2-C12alkynyl-, C1-C6alkyl-B—C3-C8cycloalkyl-, C2-C6alkenyl-B—C3-C8cycloalkyl-, C2-C6alkynyl-B—C3-C8cycloalkyl-, C3-C8cycloalkyl-B—C3-C8cycloalkyl-, benzyl-B—C3-C12cycloalkyl-, phenyl-B—C3-C12cycloalkyl-, all of which, in turn, are mono- to poly-substituted by substituents independently selected from the group consisting of halogen, cyano, hydroxy, mercapto, C1-C6 haloalkyl, C1-C6 alkoxy, formyl, C2-C6 alkylcarbonyl, C1-C6 alkylthio, C1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl; or R5 is A-, A-(C1-C6alkyl)-, A-O—(C1-C6alkyl)-, A-(C3-C6alkenyl)-, A-O—(C4-C6alkenyl)-, A-(C3-C6-alkynyl)-, A-O—(C4-C6alkynyl)-, A-(C3-C8cycloalkyl)- or A-O—(C3-C8cycloalkyl)-; A is a three- to ten-membered monocyclic or fused bicyclic ring system which can be aromatic, partially saturated or fully saturated and can contain 1 to 4 hetero atoms selected from the group consisting of nitrogen, oxygen and sulphur, it not being possible for each ring system to contain —O—O—, —S—S— and —O—S— fragments, and it being possible for the three- to ten-membered ring system to be itself mono- or polysubstituted A1) by substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxy, mercapto, azido, formyl, carboxy, ═O, ═S, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C3-C8 cycloalkyl, C1-C6 haloalkyl, C2-C6 haloalkenyl, C2-C6 haloalkynyl, C3-C8 halocycloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C3-C6 alkenyloxy, C3-C6 haloalkenyloxy, C3-C6 alkynyloxy, C3-C8 cycloalkyloxy, benzyl, benzyloxy, phenyl and phenoxy, where the benzyl, benzyloxy, phenyl and phenoxy, in turn, may be mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxy, mercapto, amino, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl; or A2) by substituents independently selected form the group consisting of (R14)S(═O)(═NR13)—, (R14)(R15)S(═O)═N—; —Si(R51)(R52)(R53), —NR57R58, —C(═O)NR57R58, —C(═S)NR57R58, HC(═NOR59)—, (C1-C6alkyl)C(═NOR59)—, (C1-C6haloalkyl)C(═NOR59)—, (C1-C6alkyl)C(═NOR59)C1-C6alkyl-, (C1-C6haloalkyl)C(═NOR69)C1-C6alkyl-, N(C1-C6alkyl)aminosulfonyl and N,N-di(C1-C6alkyl)aminosulfonyl; or A3) by substituents independently selected from the group consisting of formyl, C2-C7 alkylcarbonyl, C2-C7 haloalkylcarbonyl, C3-C7 alkenylcarbonyl, C3-C7 haloalkenylcarbonyl, C4-C9 cycloalkylcarbonyl, C4-C9 halocycloalkylcarbonyl, C2-C7 alkoxycarbonyl, C2-C7 haloalkoxycarbonyl, C3-C7 alkenyloxycarbonyl, C3-C7 alkynyloxycarbonyl, C4-C9 cycloalkoxycarbonyl, C2-C7 alkylthiocarbonyl and benzyloxycarbonyl, and benzyloxycarbonyl mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl and C1-C6 alkoxy; or A4) by substituents independently selected from the group consisting of hydroxyl, C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkynyl, C1-C4 alkoxy, halogen, C1-C4 haloalkyl, C2-C4 haloalkenyl, cyano, benzyl, phenyl, ═C(R36′)2, ═N—OH, ═N—O—C1-C4-alkyl, ═N—O—C3-C4 alkenyl, ═N—O—C3-C4 alkynyl, ═N—O—C1-C4 haloalkyl, ═N—O—C3-C4 haloalkenyl, ═N—O-benzyl and ═N—O-phenyl, wherein the ═N—O-benzyl and ═N—O-phenyl are optionally substituted by one or more group selected from the group consisting of halogen, methyl, halomethyl; or R5 is —N═C(R8)(R9); or R5 is a C8-C11 spirobicyclic system containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O atoms, which is optionally substituted by one or more groups independently selected from halogen, CN, NO2, OH, SH, CHO, COOH, tri(C1-C6-alkyl)silyl, C1-C6 alkyl, —CH(CH3)—CH2—CH2—CH3, —CH—CH(CH3)—CH2—CH3, —CH2—CH2—CH(CH3)—CH3, —CH2—CH2—CH(CH3)2, —CH(CH3)—CH(CH3)2, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C7-alkylcarbonyl, C2-C7-alkoxycarbonyl, C4-C7-alkenyloxycarbonyl, C4-C7-alkynyloxycarbonyl, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, ═O, —C(═O)NH2, —C(═O)NH(CH3), —C(═O)N(CH3)2 and —C(═S)NH2; R6 is selected from hydrogen and SH; R7 is hydrogen, halogen or C1-C4 alkyl; R8 and R9, independently from each other, are hydrogen, halogen, cyano, C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkynyl, C1-C12 alkoxy, formyl, C2-C12 alkylcarbonyl, C3-C12 alkenylcarbonyl, carboxy, C2-C12 alkoxycarbonyl and C4-C12 alkenyloxycarbonyl, or C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkynyl, C1-C12 alkoxy, C2-C12 alkylcarbonyl, C3-C12 alkenylcarbonyl, C2-C12 alkoxycarbonyl and C4-C12 alkenyloxycarbonyl mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, nitro, hydroxy, mercapto, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl; or R8 and R9 together from a C2-C8 alkylene bridge which may optionally be mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, C1-C6 alkyl and C1-C6 haloalkyl; or R8 and R9, independently from each other, are the groups A-, A-O— or A-(C1-C6alkyl)-; R10 is H, C1-C4 alkyl, C2-C4 alkenyl or C1-C4 haloalkyl; R13 is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 alkenyl, C3-C6 haloalkenyl, C3-C6 alkynyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, phenyl and benzyl, or is phenyl and benzyl mono- to polysubstituted by halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl or C1-C6 alkoxy; R14 and R15, independently of each other, are C1-C6 alkyl, C3-C8 cycloalkyl, C1-C6 haloalkyl, C3-C8 halocycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, benzyl or phenyl, or benzyl or phenyl independently of each other, substituted by substituents selected from the group consisting of halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl and C1-C6 alkoxy; R51, R52, R53, independently of each other, are halogen, cyano, C1-C6 alkyl, C2-C6 alkenyl, C3-C8 cycloalkyl, C5-C8 cycloalkenyl, C2-C6 alkynyl, C1-C6 alkoxy, benzyl or phenyl; R54, R55, R56, independently of each other, are C1-C6 alkyl, C3-C6 alkenyl, C3-C8 cycloalkyl, C3-C6 alkynyl, benzyl or phenyl; R57 and R58, independently of each other, are hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 alkenyl, C3-C6 haloalkenyl, C3-C6 alkynyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, phenyl or benzyl, where phenyl or benzyl for their part may be mono- to polysubstituted on the phenyl ring by substituents independently selected from the group consisting of halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl and C1-C6 alkoxy, or R57 and R58 together with their interconnecting nitrogen atom are aziridino, azetidino, pyrazolino, pyrazolidino, pyrrolino, pyrrolidino, imidazolino, imidazolidino, triazolino, tetrazolino, piperazino, piperidino, morpholino, thiomorpholino, each of which, in turn, may be mono- or polysubstituted by substituents selected from the group consisting of methyl, halogen, cyano; R59 is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 alkenyl, C3-C6 haloalkenyl, C3-C6 alkynyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, benzyl and phenyl, and benzyl and phenyl mono- to polysubstituted by halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl or C1-C6 alkoxy; R60 is hydrogen, C1-C6 alkyl, C3-C8 cycloalkyl, C1-C6 haloalkyl, C3-C8 halocycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, benzyl or phenyl, or benzyl or phenyl mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl and C1-C6 alkoxy; R62 is hydrogen, C1-C6 alkyl, C3-C8 cycloalkyl, C1-C6 haloalkyl, C3-C8 halocycloalkyl, C3-C6 alkenyl, C3-C6 alkynyl, benzyl or phenyl, or benzyl or phenyl mono- to polysubstituted by substituents independently selected from the group consisting of halogen, cyano, hydroxy, C1-C6 alkyl, C1-C6 haloalkyl and C1-C6 alkoxy; each R36′ is independently selected from hydrogen, halogen and C1-C4 alkyl; and agronomically acceptable salts/metallic complexes/metalloidic complexes/isomers/structural isomers/stereo-isomers/diastereoisomers/enantiomers/tautomers/N-oxides of those compounds; and component B) is a strobilurin fungicide, a sterol biosynthesis inhibitor, a triazole fungicide, a pro-triazole fungicide, a DMI fungicide, a SDHI fungicide, or a compound selected from the group consisting of Chlorothalonil, Fludioxonil, Cyprodinil, Mandipropamid, Fluazinam, Procymedone, Carbendazim, Abamectin, Clothianidin, Emamectin benzoate, Imidacloprid, Tefluthrin, Mefenoxam, Orocymedone, Thiamethoxam, Lambda-cyhalothrin, Gamma-cyhalothrin, Profenofos, Lufenuron, Diflubenzuron, Cypermethrin, Novaluron, Bifenthrin, Methomyl, Chlopyrifos, Methamidophos, Endosulfan, Betacyfluthrin, Triflumuron, Teflubenzuron, SulcotrioneAcephat, Glyphosate, Glufosinate, Mesotrione, Tembotrione, Sulcotrione, Auxins, Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol, Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone, Manganese, Cyflufenamid, Tebufloquin and Copper. |
