ELECTROCHEMICAL pH MEASUREMENT

摘要

An electrode for the determination of pHis made by depositing a phenolic compound on a conductive substrate,where the phenolic compound has a phenolic hydroxy group attached to a carbon atom on an aromatic ring and also has an oxygen atom connected through one other atom to an adjacent carbon atom of the aromatic ring such that thisoxygen atom can form a hydrogen bond to the phenolic hydroxy group; and then electrochemically oxidising the immobilized phenolic compound in a one electron one proton oxidation so as to form a polymeric, water-insoluble, redox-active deposit on the conductive substrate. The electrode is useful for electrochemical determination of p H and is capable of measuring pH of an unbuffered aqueousliquid.