Block coordination copolymers

摘要

The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

主权项

1. A process for separating a first component from a second component of a mixture comprising contacting the mixture with a coordination copolymer comprising at least a first region of a first coordination polymer having a first x-ray diffraction pattern and second region of a second coordination polymer having a second x-ray diffraction pattern wherein the first and second coordination polymers are not identical and wherein the x-ray diffraction pattern of the coordination copolymer comprises both the first x-ray diffraction pattern and the second x-ray diffraction pattern.