发明名称 HYDROSILYLATION REACTION INHIBITORS, AND USE THEREOF FOR PREPARING STABLE CURABLE SILICONE COMPOSITIONS
摘要 Methods of using inhibitor compounds are described. In particular, methods of using inhibitor compounds to inhibit the curing of a silicone composition that is a precursor of a silicone elastomer produced by a hydrosilylation reaction are described.
申请公布号 US2014329099(A1) 申请公布日期 2014.11.06
申请号 US201214128414 申请日期 2012.06.19
申请人 Marrot Sébastien;Maadadi Yassine 发明人 Marrot Sébastien;Maadadi Yassine
分类号 C09D7/12;C08K5/42;C09K15/12;C08K5/05 主分类号 C09D7/12
代理机构 代理人
主权项 1. A silicone composition X capable of curing by means of a polyaddition reaction, the composition comprising: (1) at least one organopolysiloxane A comprising, per molecule, at least two alkenyl radicals bonded to silicon atoms, (2) at least one organohydropolysiloxane B comprising, per molecule, at least two hydrogen atoms bonded to silicon atoms, (3) at least one catalyst C which is a platinum compound and even more preferentially a Karstedt platinum, in which the amount by weight of platinum of the catalyst C relative to the total weight of the silicone composition X is less than 50 ppm, (4) at least one inhibitor D which is capable of being obtained by mixing, optionally in situ: at least one inhibitor D1 which is an acetylenic alcohol, andat least one acid D2 which has, in aqueous solution and at 25° C., at least a pKa<−0.9, said constituents D1 and D2 being initially present in said silicone composition X in amounts sufficient to: maintain the inhibition of the catalyst C so as to prevent the formation of a gel or of an elastomer when said silicone composition X is stored at ambient temperature, andallow the partial or complete degradation of said acetylenic alcohol D1 by chemical reaction between the inhibitor D1 and the acid D2 when the silicone composition X is cured by heating at a temperature between 70° C. and 200° C.
地址 Lyon FR