主权项 |
1. A functionalized nanoparticle comprising on a surface covalently bound radical of the formula (I) and a covalently bound radical of formula (II): wherein the functionalized nanoparticle is a SiO2 nanoparticle; X is oxygen; sulfur; or R1 is a photoinitiator having as formula selected from the group consisting of R2 and R3 are each independently hydrogen; C1-C25 alkyl; C3-C25alkyl, which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; C7-C9-phenylalkyl; —OR5; R4 is hydrogen; C1-C25alkyl; or C3-C25alkyl, which is interrupted by oxygen or sulfur; R5 is hydrogen; C1-C25alkyl; which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; C7-C9phenylalkyl;or the nanoparticle surface,
R6 and R7 are each independently hydrogen; C1-C25alkyl; C3-C25alkyl, which is interrupted by oxygen or sulfur; C2 phenyl; C7-C9-phenylalkyl; or —OR5; R8, R9 and R10 are each independently hydrogen; C1-C25alkyl; C3-C25alkyl, which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; or C7-C9phenylalkyl; R11 is C1-C25alkyl; C3-C25alkyl, which is interrupted by oxygen, sulfur oramino-, mercapto-, or hydroxyl substituted C2-C24alkyl; amino-, mercapto-, or hydroxyl substituted C2-C24alkyl, which is interrupted by oxygen, sulfur, orC2-C24alkenyl; C5-C12cycloalkyl; C5-C2cycloalkenyl; a polymerizable group; or a polymer;
R12 and R13 are each independently hydrogen; C1-C25alkyl; C3-C25alkyl, which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; C7-C9-phenylalkyl; —OR15; R14 is hydrogen; C1-C25alkyl; or C3-C25alkyl, which is interrupted by oxygen or sulfur; R15 is hydrogen; C1-C25alkyl; C3-C75alkyl, which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; C7-C9-phenylalkyl;or the nanoparticle surface,
R16 and R17 are each independently hydrogen; C1-C25alkyl; C3-C25alkyl, which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; C7-C9-phenylalkyl; —OR15, R18, R19 and R20 are each independently hydrogen; C1-C25alkyl; C3-C25alkyl, which is interrupted by oxygen or sulfur; C2-C24alkenyl; phenyl; or C7-C9phenylalkyl, R43 and R44 are each independently hydrogen; C1-C18alkoxy; or di(C1-C4alkyl)amino; R45 is hydrogen; C1-C18alkyl; or C1-C18alkoxy; R63 and R64 are each independently hydrogen; C1-C18alkoxy; C1-C4alkylthio; morpholinyl; or C7-C9phenylalkyl of phenyl; R65 and R66 are each independently C1-C18alkyl; R67 is C2-C4alkylene; R68 is hydrogen or C1-C18alkyl; R69 is C3-C7alkylene; R70 and R71 are each independently C1-C8alkyl or C7-C9-phenylalkyl; R72 and R73 are each independently C1-C8alkyl; or R72 and R73 are together —CH2CH2—O—CH2CH2— thus forming with the nitrogen atom to which they are attached a morpholinyl ring; R74 is hydrogen; C1-C18alkyl; or C7-C9-phenylalkyl; and n is 1, 2, 3, 4, 5, 6, 7 or 8. |