| 主权项 |
1. A composition comprising 1) an electrode comprising a covalently attached electroactive complex (EAM), said EAM comprising a transition metal and at least one cyano ligand; or 2) an electrode comprising a) a first species comprising a functional group, and b) an EAM, said EAM comprising a transition metal and at least one cyano ligand; or 3) a) a first anchor, b) a charge-neutralizing ligand linked to said first anchor, c) an EAM covalently attached to said charge-neutralizing ligand, and d) a capture ligand; or 4) an electrode comprising a self-assembled monolayer (SAM), wherein said SAM comprises a compound having the formula: Anchor-Spacer 1-EAM-Spacer 2-CL (II), wherein said anchor is linked to said electrode group through a disulfide group, EAM is an electroactive moiety comprising a solvent accessible redox compound, CL is a capture ligand, Spacer 1 is either insulating or conducting, and Spacer 2 is optional; or 5) an array of electrode, each electrode comprising a compound having the formula: Anchor Spacer 1 EAM (Spacer (I), wherein said anchor comprises a cyclic-disulfide group, EAM is an electroactive moiety comprising a solvent accessible redox compound, CL is a capture ligand, Spacer 1 is either insulating or conduction, and n=0 or 1. |
