发明名称 PRODUCTION METHOD FOR POLYAMIDE
摘要 The present invention provides a production method for polyamides, whereby adherance of matter to a reaction tank gas phase section and a vapor tube is suppressed and little mixing in of unmelted matter caused by said adhered matter occurs in the obtained product, and in which: a diamine component including at least 70 mol pcnt paraxylene diamine and a dicarboxylic acid component including at least 70 mol pcnt C6-18 aliphatic dicarboxylic acid are directly melt-polymerized in the absence of a solvent, in a batch-type reaction device comprising agitation blades; (1) the diamine component and the dicarboxylic acid component are reacted under pressure conditions of 0.2-0.5 MPa (Abs); (2) the gas phase section temperature inside the reaction tank during the reaction is held at 200�C or higher; (3) inside the reaction tank is agitated such that the agitation Froude number indicated by a specific formula is 0.0002-0.15, from the start of the addition of the diamine component until after the completion thereof and before pressure reduction starts; and (4) agitation blades are used that do not have a structural body in the horizontal direction, or have a structural body in the horizontal direction that does not come in contact with the reaction fluid or the boundary of the gas phase section during agitation.
申请公布号 PH12014501623(A1) 申请公布日期 2014.10.20
申请号 PH12014501623 申请日期 2014.07.15
申请人 MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 TOCHIHARA, TATSUYA;SHINOHARA, KATSUMI
分类号 C08G69/28 主分类号 C08G69/28
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