发明名称 |
Self-Healing Catalysts: CO3O4 Nanorods for Fischer-Tropsch Synthesis |
摘要 |
A self-healing reaction process for a chemical reaction is provided by exposing a catalyst a reaction mixture that includes carbon monoxide and hydrogen gas such that hydrocarbons are produced. The catalyst includes Co3O4 nanorods having both Co2+ and Co3+ exposed thereon. The Co3O4 nanorods can have a spinel crystal structure such that the Co3O4 nanorods define a {110} facet having both Co2+ and Co3+ exposed thereon. During reaction conditions, water can oxidize portions of the catalyst, while the exposed Co3+ can reduce any oxidized portions of the catalyst such that the catalyst is self-healing during reaction conditions, especially when the reaction mixture further comprises water. |
申请公布号 |
US2014309316(A1) |
申请公布日期 |
2014.10.16 |
申请号 |
US201414252169 |
申请日期 |
2014.04.14 |
申请人 |
Lauterbach Jochen A.;Hattrick-Simpers Jason R.;Wen Cun |
发明人 |
Lauterbach Jochen A.;Hattrick-Simpers Jason R.;Wen Cun |
分类号 |
C07C1/04 |
主分类号 |
C07C1/04 |
代理机构 |
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代理人 |
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主权项 |
1. A self-healing reaction process, comprising:
exposing a catalyst to a reaction mixture such that hydrocarbons are produced, wherein the reaction mixture comprises carbon monoxide and hydrogen gas, and wherein the catalyst comprises Co3O4 nanorods comprising both Co2+ and Co3+ exposed thereon. |
地址 |
Columbia SC US |