发明名称 PROCESS FOR PRODUCTION OF .ALPHA.-OLEFIN LOW POLYMERS USING CHROMIUM CATALYST
摘要 The object of the present invention is to provide a production method of an .alpha.-olefin low polymer, wherein a low polymer of an .alpha.-olefin is obtained in high yield. The present invention relates to that when an inert gas is allowed to exist in a gas phase part of a reactor 10 in the proportion of from 0.010 to 50.00% by volume, and an .alpha.-olefin is subjected to low polymerization reaction in a solvent in the presence of a chromium series catalyst comprising a chromium compound (a), at lest one nitrogen-containing compound (b) selected from the group consisting of an amine, an amide and an imide, and an aluminum-containing compound (c), an unreacted .alpha.-olefin and the solvent separated from a reaction liquid are circulated into the reactor 10, and where the proportion of the inert gas in the gas phase exceeds 50.00% by volume, the inert gas is discharged outside the reaction system from a gas phase part of the reactor 10 and/or a circulation piping 21 of an unreacted .alpha.-olefin.
申请公布号 CA2672385(C) 申请公布日期 2014.10.14
申请号 CA20072672385 申请日期 2007.10.22
申请人 MITSUBISHI CHEMICAL CORPORATION 发明人 EMOTO, HIROKI;YOSHIZURU, KEI
分类号 C08F4/69;B01J31/34;B01J37/04;C07B61/00;C07C2/08;C07C11/107;C08F2/06;C08F10/00 主分类号 C08F4/69
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