| 摘要 |
FIELD: chemistry.SUBSTANCE: invention relates to a method for hydrocyanation of ethylenically unsaturated organic compounds containing at least one nitrile group, and can be used in chemical industry. The disclosed method includes performing hydrocyanation by reaction in a liquid medium with hydrocyanic acid in the presence of a catalyst containing a transition metal and an organophosphorus ligand of formulaorwhere Ris a divalent radical of general formula(III), and Rand Rdenote an aliphatic radical containing 1-6 carbon atoms, R, R, R, Rdenote a hydrogen atom, an alkyl radical having 1-12 carbon atoms, which may contain heteroatoms; an aromatic or cycloaliphatic radical which may contain heteroatoms; a carbonyl, alkoxycarbonyl or alkoxy radical; a halogen atom, a nitrile group or a haloalkyl group containing 1-12 carbon atoms, X denotes fluorine or bromine.EFFECT: novel efficient hydrocyanation method which also enables isomerisation of the obtained product.15 cl, 14 ex, 3 tbl |
