发明名称 METHOD FOR PRODUCING PROPYLENE-BASED BLOCK COPOLYMER
摘要 PROBLEM TO BE SOLVED: To provide a method for producing a propylene-based block copolymer to stably obtain a polymer with a high productivity by increasing the molecular weight of a copolymer component and increasing catalytic activity without excessively purging hydrogen gas in a continuous gas phase process.SOLUTION: There is provided a method for producing a propylene-based block copolymer which comprises steps (I) and (II) in the presence of a solid catalyst component (A), where a component (B) is added in the step (I), a hydrogen concentration is adjusted in the range of 50 to 500 ppm in the step (II) and the weight average molecular weight is adjusted to 1800000 or more. Component (A): a solid catalyst component, (I) a first step of homocopolymerizing propylene or copolymerizing ethylene or an α-olefin having 4 or more carbon atoms at more than 0 and less than 10 wt.% with propylene, (II) a second step of polymerizing propylene with ethylene or an α-olefin having 4 or more carbon atoms at 10 to 90 wt.%, Component (B): an organic aluminum compound (1) RAlX(OR)(1).
申请公布号 JP2014189689(A) 申请公布日期 2014.10.06
申请号 JP20130067779 申请日期 2013.03.28
申请人 JAPAN POLYPROPYLENE CORP 发明人 SAKAKURA AKIRA;ITO MASAAKI;MIZUKAMI SHIGEO;HOSOI TOMOHIRO
分类号 C08F297/08;C08F4/658 主分类号 C08F297/08
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