发明名称 |
SEPARATION TECHNIQUE, PHOTO-OXIDATION OF ORGANIC SUBSTRATES, AND PHOTO CATALYSTS |
摘要 |
A method for photo-oxidising an organic substrate to form an organic product is disclosed comprising: a) mixing oxygen, a supercritical fluid, a photocatalyst, a liquid fluorous solvent and an organic substrate to form a mixture; and b) irradiating the mixture to form an organic product. Also disclosed is a method for separating a photocatalyst from an organic product comprising the steps of: a) providing a mixture comprising a supercritical fluid; an organic product; a fluorous solvent; a photocatalyst; and optionally an organic substrate and optionally oxygen; wherein the organic product, fluorous solvent, photocatalyst and optional organic substrate and optional oxygen are dissolved in the supercritical fluid; and b) reducing the pressure of the mixture to a pressure below the critical pressure of the supercritical fluid in order to form a gaseous phase. |
申请公布号 |
US2014288328(A1) |
申请公布日期 |
2014.09.25 |
申请号 |
US201214358578 |
申请日期 |
2012.11.13 |
申请人 |
The University of Nottingham |
发明人 |
Poliakoff Martyn;George Mike W.;Bourne Richard A.;Han Xue;Hall Jessica F. B. |
分类号 |
C07C51/25;B01J19/12 |
主分类号 |
C07C51/25 |
代理机构 |
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代理人 |
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主权项 |
1. A method for photo-oxidising an organic substrate to form an organic product comprising the steps of:
a) mixing oxygen, a supercritical fluid, a photocatalyst, a liquid fluorous solvent and an organic substrate to form a mixture; and b) irradiating the mixture to form an organic product. |
地址 |
Nottinghamshire GB |