Energy conservation in heavy-hydrocarbon distillation

摘要

An aromatics complex producing one or more xylene isomers offers a large number of opportunities to conserve energy by heat exchange within the complex. One previously unrecognized opportunity is through providing two parallel distillation columns operating at different pressures to separate C8 aromatics from C9+ aromatics. The parallel columns offer additional opportunities to conserve energy within the complex.

主权项

1. A distillation apparatus comprising two distillation columns for separating C8-aromatic components from C9-and-heavier aromatic components comprising:
(a) a first distillation column and a reboiler, the first distillation column at a first pressure and having an inlet and having a bottom portion in fluid communication with the reboiler; a reformate splitter providing a higher boiling feed stream to the inlet of the first distillation column; (b) a second distillation column and an isomerization reactor, the second distillation column operating at a second pressure higher than the first pressure and having an inlet and having a top portion in fluid communication with an overhead conduit; the isomerization reactor providing at least one lower-boiling feed stream to the inlet of the second distillation column so that the higher-boiling feed stream has a higher content of C9-and-heavier aromatics than the at least one lower-boiling feed stream; and (c) the overhead conduit from the second distillation column providing fluid communication to the reboiler of the first distillation column, wherein the reboiler of the first distillation column has an enhanced nucleate boiling surface.