发明名称 WATER-INSOLUBLE RUTHENIUM CATALYST COMPOSITION FOR USE IN AQUEOUS HYDROGENATION REACTIONS
摘要 The invention relates to a method for converting a precatalyst complex to an active catalyst complex, wherein the precatalyst complex and the active catalyst complex comprise a ruthenium atom and an optically active ligand that is insoluble in water, and the active catalyst complex furthermore comprises a monohydride and a water molecule. The method comprises the steps of providing water as an activation solvent system with a pH value equal or below 2, and solving said precatalyst complex, an acid, and hydrogen therein. The invention further relates to a method for manufacturing a catalyst composition, a method for hydrogenating a substrate molecule and a reaction mixture.
申请公布号 WO2014135605(A1) 申请公布日期 2014.09.12
申请号 WO2014EP54291 申请日期 2014.03.05
申请人 JOST, SONJA 发明人 JOST, SONJA
分类号 B01J31/24;C07C29/145 主分类号 B01J31/24
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