发明名称 METHOD FOR PRODUCING (METH)ACRYLIC ACID ESTER
摘要 PROBLEM TO BE SOLVED: To provide a method for producing a (meth)acrylic acid ester stably and efficiently over a long period of time by preventing blocking operation trouble in reboiler of a heavy component decomposer in which a (meth)acrylic acid ester and a heavy component are separated by distillation from an esterification solution containing a (meth)acrylic acid ester obtained by reacting (meth)acrylic acid and alcohol in the presence of an acid catalyst and the heavy component is decomposed and esterified to collect valuable materials.SOLUTION: When a valuable material containing a (meth)acrylic acid ester and alcohol is collected by introducing a mixed liquid of a heavy component and an acid catalyst-containing liquid into a heavy component decomposer, followed by subjecting to decomposition and esterification, the acid catalyst concentration is set to satisfy the following conditions (1) and/or (2): (1) the acid catalyst concentration of the acid catalyst-containing liquid is 28 wt.% or less and (2) the acid catalyst concentration of the mixed solution is 1 to 3 wt.%.
申请公布号 JP2014162767(A) 申请公布日期 2014.09.08
申请号 JP20130035874 申请日期 2013.02.26
申请人 MITSUBISHI CHEMICALS CORP 发明人 KANEKO DAISAKU
分类号 C07C67/60;C07C67/08;C07C69/54 主分类号 C07C67/60
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