发明名称 Method for producing hydrocarbon-producing catalyst, hydrocarbon-producing catalyst, and method for producing hydrocarbon
摘要 The present invention relates to a method for producing a hydrocarbon-producing catalyst for producing a hydrocarbon from a mixed gas of carbon monoxide and hydrogen and provides a method for producing, with stability and at high productivity, a hydrocarbon-producing catalyst with which the rate of conversion of carbon monoxide to hydrocarbon is high, the methane selectivity is low, the high activity can be maintained over a long period, the desorption of the active metal is unlikely to occur, and the durability is excellent. The method includes a precursor film forming step of putting a sol solution of an active metal compound and a metal oxide precursor in contact with a heated catalyst carrier 2 to form a precursor film on a surface of the catalyst carrier 2, and a hydrolysis step of gelling the precursor film by hydrolysis to form a metal oxide gel film 4, with the active metal 6 dispersed uniformly, on the surface of the catalyst carrier 2.
申请公布号 US8822369(B2) 申请公布日期 2014.09.02
申请号 US200913130882 申请日期 2009.11.27
申请人 Kitakyushu Foundation for the Advancement of Industry, Science and Technology 发明人 Li Xiaohong;Yuuda Hisashi
分类号 C07C1/20;B01J37/02;B01J23/75;B01J35/02;B01J21/08;B01J35/00;C10G2/00;B01J37/03 主分类号 C07C1/20
代理机构 Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. 代理人 Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
主权项 1. A method for producing a hydrocarbon-producing catalyst, the method comprising: putting a sol solution of an active metal compound and a metal oxide precursor in contact with a heated catalyst carrier, to form a precursor film on a surface of the catalyst carrier; and gelling the precursor film by hydrolysis, to form a metal oxide gel film, with the active metal dispersed uniformly, on the surface of the catalyst carrier, wherein a molar ratio of the active metal with respect to the metal oxide, active metal/metal oxide, in the metal oxide gel film with the active metal dispersed uniformly, is 1.5 to 2.4.
地址 Kitakyushi-shi JP