发明名称 |
Method for producing hydrocarbon-producing catalyst, hydrocarbon-producing catalyst, and method for producing hydrocarbon |
摘要 |
The present invention relates to a method for producing a hydrocarbon-producing catalyst for producing a hydrocarbon from a mixed gas of carbon monoxide and hydrogen and provides a method for producing, with stability and at high productivity, a hydrocarbon-producing catalyst with which the rate of conversion of carbon monoxide to hydrocarbon is high, the methane selectivity is low, the high activity can be maintained over a long period, the desorption of the active metal is unlikely to occur, and the durability is excellent. The method includes a precursor film forming step of putting a sol solution of an active metal compound and a metal oxide precursor in contact with a heated catalyst carrier 2 to form a precursor film on a surface of the catalyst carrier 2, and a hydrolysis step of gelling the precursor film by hydrolysis to form a metal oxide gel film 4, with the active metal 6 dispersed uniformly, on the surface of the catalyst carrier 2. |
申请公布号 |
US8822369(B2) |
申请公布日期 |
2014.09.02 |
申请号 |
US200913130882 |
申请日期 |
2009.11.27 |
申请人 |
Kitakyushu Foundation for the Advancement of Industry, Science and Technology |
发明人 |
Li Xiaohong;Yuuda Hisashi |
分类号 |
C07C1/20;B01J37/02;B01J23/75;B01J35/02;B01J21/08;B01J35/00;C10G2/00;B01J37/03 |
主分类号 |
C07C1/20 |
代理机构 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. |
代理人 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. |
主权项 |
1. A method for producing a hydrocarbon-producing catalyst, the method comprising:
putting a sol solution of an active metal compound and a metal oxide precursor in contact with a heated catalyst carrier, to form a precursor film on a surface of the catalyst carrier; and gelling the precursor film by hydrolysis, to form a metal oxide gel film, with the active metal dispersed uniformly, on the surface of the catalyst carrier, wherein a molar ratio of the active metal with respect to the metal oxide, active metal/metal oxide, in the metal oxide gel film with the active metal dispersed uniformly, is 1.5 to 2.4. |
地址 |
Kitakyushi-shi JP |