发明名称 Selenium-based monomers and conjugated polymers, methods of making, and use thereof
摘要 Substituted selenophene monomers, and polymers and copolymers having units derived from a substituted selenophene are disclosed. Also provided are methods of making and using the same.
申请公布号 US8822635(B2) 申请公布日期 2014.09.02
申请号 US201313923502 申请日期 2013.06.21
申请人 The University of Connecticut 发明人 Sotzing Gregory A.;Dey Tanmoy
分类号 C08G65/00 主分类号 C08G65/00
代理机构 Cantor Colburn LLP 代理人 Cantor Colburn LLP
主权项 1. A compound, comprising: a monomer according to any one of structure (I), (Ia), (II), and (IIa): wherein each instance of Q is O or S; X is chloro, bromo, or iodo; each of R1a, R1b, R2a, R2b, R3, and R4 independently is hydrogen; C1-C20 alkyl, C1-C20 haloalkyl, aryl, C1-C20 alkoxy, C1-C20 haloalkoxy, aryloxy, —C1-C10 alkyl-O—C1-C10alkyl, —C1-C10alkyl-O-aryl, —C1-C10alkyl-aryl; or hydroxyl; with the proviso that at least one of R1a, R1b,R2aR2b, R3, and R4is not hydrogen, and when R1a, R1b, R2a, and R2b are all hydrogen, then at least one of R3 and R4 is other than hydrogen, C1-C20 alkyl, or —C1-C10 alkyl-aryl; wherein the C1-C20 alkyl, C1-C20 haloalkyl, aryl, C1-C20 alkoxy, C1-C20 haloalkoxy, aryloxy, —C1-C10 alkyl-O—C1-C10 alkyl,—C1-C10 alkyl-O-aryl, —C1-C10 alkyl-aryl group each may be optionally substituted with one or more of C1-C20 alkyl; aryl; halogen; hydroxyl; —N—(R7)2 wherein each R7 is independently hydrogen or C1-C6 alkyl; cyano; nitro; —COOH; —S(═O)C0-C10 alkyl; or —S(═O)2C0-C10 alkyl.
地址 Farmington CT US
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