Copolymer for organic antireflective film, monomer, and composition comprising the copolymer

摘要

Disclosed are a copolymer for organic antireflective films containing a repeating unit represented by the following formula (1), a monomer for the copolymer, and an organic antireflective film composition including the copolymer:;
wherein in the formula (1), R1, R2, R3, A, m and n respectively have the same meanings as defined in the detailed description of the invention. The organic antireflective film composition including the copolymer for organic antireflective films has an increased refractive index and exhibits excellent effects when produced into an antireflective film, and hydrophilicity and hydrophobicity of the coating film produced from the composition can be regulated, so that excellent compatibility with resists can be obtained.

主权项

1. A copolymer for organic antireflective films, comprising a repeating unit represented by the following formula (1): wherein in the formula (1), R1 represents any one selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, and a heteroalkyl group having 1 to 6 carbon atoms;
R2 represents any one selected from the group consisting of CR′R″, NR′, O and S; R′ and R″ each independently represent any one selected from the group consisting of a hydrogen atom and an alkyl group having 1 to 5 carbon atoms;R3 is any one selected from the group consisting of groups represented by the following formulas (1-1) to (1-8):m and n satisfy the following relations: m+n=1, 0.05R5 represents any one selected from the group consisting of a hydrogen atom, an alkyl group, a heteroalkyl group, a cycloalkyl group, a heterocycloalkyl group, an aryl group, a heteroaryl group, an arylalkyl group and a heteroarylalkyl group, and at least one hydrogen atom contained in R5 is substituted by any one selected from the group consisting of a hydroxyl group, a carboxyl group, a halogen atom, a cyano group, a nitro group and combinations thereof; and wherein in the formula (3), R6 represents any one selected from the group consisting of a hydrogen atom, an alkyl group, a cycloalkyl group, a heteroalkyl group and a cycloheteroalkyl group wherein in the formulas (1-1) to (1-8),X11, X21, X22, X31, X32, X33, X51, X52, X61, X62, X71, X72, X73, X81 and X82 each independently represent any one selected from the group consisting of a halogen atom, a cyano group, a nitro group, a phenyl group and perfluoroalkyl group;R′″ represents any one selected from the group consisting of a hydrogen atom and a methyl group; X41 represents a halogen atom; a represents an integer from 1 to 3; b represents an integer from 1 to 3, the sum a+b is 3;X63 represents any one selected from the group consisting of O, NR′, S and CO;p11 represents an integer from 1 to 5;p21 and p22 each independently represent an integer from 1 to 4, the sum of p21 and p22 does not exceed 5;p31 to p33 each independently represent an integer from 1 to 3, the sum of p31 to p33 does not exceed 5;p41 represents an integer from 1 to 5;p51 and p52 each independently represent an integer from 1 to 5, the sum of p51 and p52 does not exceed 9;p61 and p62 each independently represent an integer from 1 to 5, the sum of p61 and p62 does not exceed 9;p71 and p73 each independently represent an integer from 1 to 5, p72 represents an integer from 1 to 2, the sum of p71 to p73 does not exceed 9;p81 represents an integer from 1 to 4; p82 represents an integer from 1 to 3; and the sum of p81 and p82 does not exceed 6, and wherein the copolymer has a weight-average molecular weight as calculated relative to polystyrene standards of 5,000 g/mol to 20,000 g/mol.